Astat w chemii i medycynie

• Autorzy: Pruszyński M. , Bilewicz A.

Warianty tytułu

EN

Astatine in chemistry and medicine

• Języki publikacji: PL

Abstrakty

EN

Astatine, element 85, is the heaviest halogen. The first synthesis of' ²¹¹At was performed by Corson by irradiation of 209Bi target with a-particles. Most of the chemical studies have been done using this isotope. Astatine is one of the most difficult clements to study from a chemical point of view, and our knowledge of its compounds is rather incomplete compared to what we know about other elements. For this there are several reasons, especially that the astatine have very short-lived isotopes which make it impractical to obtain weighable amounts of the element. Therefore, chemical studies of astatine can be performed only with very low concentrations - concentrations much less than the impurity levels commonly present in an experimental system. Radionuclide ²¹¹At has been newly discovered within development of nuclear medicine, because it has a lot of diserable and advantageous properties, that are required in cancer therapy. It's potential application was recognized due to the radiotoxicity associated with emission of a particle and that of its daughter ²¹¹Po. This review presents current knowledge about chemistry of astatine, especially its inorganic chemistry (e.g. valence states, anionic complexes of astatine with halogenides and pseudohalogenides ions etc.). Moreover, information is given about synthesis of some organic compounds of astatine. Special attention was paid on labelling of biologically active molecules with ²¹¹At and their potential applications in nuclear medicine.

Słowa kluczowe

PL

astat; właściwości fizykochemiczne astatu; medycyna nuklearna

EN

astatine; physical and chemical properties

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Wiadomości Chemiczne
• Rocznik: 2004
• Tom: [Z] 58, 5-6
• Strony: 403--425
• Opis fizyczny: Bibliogr. 100 poz., schem., tab., wykr.

Twórcy

autor

Pruszyński M.

• Zakład Radiochemii, Instytut Chemii I Techniki Jądrowej, ul. Dorodna 16, 03-195 Warszawa

autor

Bilewicz A.

• Zakład Radiochemii, Instytut Chemii I Techniki Jądrowej, ul. Dorodna 16, 03-195 Warszawa

Bibliografia

• [1] D.R. Corson, K.R. Mackenzie, E. Segre, Phys. Rev., 1940, 57, 672.
• [2] D.R. Corson, K.R. Mackenzie, E. Segre, Nature, 1947,159, 24.
• [3] B.N. Belayev, Yung-Ya Wang, E.N. Sinotova, L. Nemet, V.A. Khalkin, Radiokhimiya, 1960, 5, 603.
• [4] E.F. Momeyev, E.K. Hyde, J. Inorg. Nuclear Chem., 1995,1,274.
• [5] A.N. Niesmiejanow, Radiochemia, PWN, Warszawa 1975.
• [6] J.C. Bailar, H.J. Emeleus, R. Nyholm, A.F. Trotman-Dickenson, Comprehensive Inorganic Chemistry, Pergamon Press, Oxford 1973.
• [7] P. Hoff, Act. Phys. Polon., 2000, B31, 33.
• [8] R.M. Lambrecht, S. Mirzadeh, Int. J. Appl. Radiat. Isot., 1985, 36, 443.
• [9] R.H. Larsen, B.W. Wieland, M.R. Zalutsky, Appl. Radiat. Isot., 1996, 47, 135.
• [10] G. Henriksen, S. Messelt, E. Olsen, R.H. Larsen, Appl. Radiat. Isot., 2001, 54, 839.
• [11] G.J. Meyer, R.M. Lambrecht, Int. J. Appl. Radiat. Isot., 1980, 31, 351.
• [12] V.M. Vachtel, G.V. Vinel, C. Vinel, IX Gromova, A.F. Norseev, V.A. Khalkin, V.G. Tschumn, Joint Institute of Nuclear Research, Dubna, Report: JINR 12-8996, 1975.
• [13] G.J. Meyer, K. Rossler, Radiochem. Radioanal. Lett., 1976, 25, 1976.
• [14] S. Lindegren, T. Back, HJ. Jensen, Appl. Radiat. Isot., 2001, 55, 157.
• [15] W. Finkelnburg, F. Stem, Phys. Rev., 1950,77,303.
• [16] M.F.C. Ladd, W.H. Lee, J. Inorg. Nuclear Chem., 1961, 20, 163.
• [17] E.P. Ozhigow, J. Gen. Chem., 1964,34, 3519.
• [18] R. McLaughlin, J. Opt. Soc. Amer., 1964, 54, 965.
• [19] R.W. Kiser, J. Chem. Phys., 1960, 33, 1265.
• [20] R.E. Honig, D. A. Kramer, Vapour Pressure Curves of the Elements, Sheet C, RCA Laboratories, 1969.
• [21] GA. Krestov, Radiokhimiya, 1962, 4, 690.
• [22] L. Genov, J. Gen. Chem., 1959, 29, 683.
• [23] E.H. Appelman, J. Am. Chem. Soc., 1961, 83, 805.
• [24] E.H. Appelman, E.N. Sloth, M.H. Studier, Inoig. Chem., 1966, 5, 766.
• [25] E.H. Appelman, UCRL - 9025, January, 1960.
• [26] A.H.W. Aten Jr., Adv. Inorg. Chem. Radiochem., 1964, 6, 207.
• [27] M.S. Sultana, A. Toyoshima, A. Mito, N. Takahashi, H. Baba, H. Watarai, J. Radioanal. Nucl. Chem., 2000,243, 631.
• [28] M.S. Sultana, A. Toyoshima, N. Takahashi, H. Baba, J. Radioanal. Nucl. Chem., 2001,247, 193.
• [29] B. Rumler, N. Trautmann, G. Herrmann, Radiochim. Acta 1989, 47, 91.
• [30] G.L. Johnson, R.F. Leiniger, E. Segre, J. Chem. Phys., 1949,17, 1.
• [31] W.M. Latimer, The Oxidation States of the Elements and Their Potentials in Aqueous Solutions, Prentice Hall, New York 1952.
• [32] A. Cavallero, K. Roessler, Radiochim. Acta, 1989,47, 109.
• [33] A. Cavallero, K. Roessler, Radiochim. Acta, 1989,47, 113.
• [34] E.H. Appelman, Int. Rev. Sci. Inorg. Chem., Series 1, Vol. 3, ed. V. Gutmann, Butterworths, London 1972.
• [35] A.J. Bard, Encyclopedia of Electrochemistry of the Elements, Vol. 1, Marcel Dekker Inc., New York 1973.
• [36] G.L. Johnston, C.W. Asling, P.W. Durbin, J.G. Hamilton, University of California Radiation Laboratory, 1955, UCRL-3013, 35.
• [37] G.W.M. Visser, Radiochim. Acta, 1989,47, 97.
• [38] G.W.M. Visser, E.L. Diemer, Radiochim. Acta, 1983, 33, 145.
• [39] M. Milanov, V. Doberenz, V.A. Khalkin, A. Marinov, J. Radioanal. Nucl. Chem. Articles, 1984,83, 291.
• [40] I. Dreyer, R. Dreyer, V.A. Khalkin, Radiochem. Radioanal. Lett., 1978,36, 389.
• [41] F.A. Cotton, G. Wilkinson, C.A. Murillo, M. Bochmann, Advanced Inorganic Chemistry, 6th Edition, John Willey and Sons, New York 1999.
• [42] I. Dreyer, R. Dreyer, V.A. Khalkin, M. Milanov, Radiochem. Radioanal. Lett., 1979,40, 145.
• [43] V.A. Khalkin, Yu.V. Norseev, V.D. Nefedov, M.A. Toropova, VI. Kuzin, Dokl. Akad. Nauk SSSR, 1970,195, 855.
• [44] G.A. Nagy, P. Groz, V.A. Khalkin, Yu.V. Norseev, Do-Kim Toung, Kozp. Fiz. Kut. Intez. Kozlem, 1970, 18, 173.
• [45] G.A. Nagy, V.A. Khalkin, Yu.V. Norseev, Magy. Kem. Foly, 1967,73, 191.
• [46] I. Dreyer, R. Dreyer, V.A. Khalkin, Radiochem. Radioanal. Letters, 1978,35, 257.
• [47] E.H. Appelman, J. Chem. Phys., 1961, 63, 325.
• [48] R. Dreyer, I. Dreyer, W. Doberenz, S. Fischer, Isotopenpraxis, 1986,22, 81.
• [49] R. Dreyer, I. Dreyer, M. Pfeiffer, F. Rosch, Radiochem. Radioanal. Letters, 1982, 4, 207.
• [50] S. Fischer, R. Dreyer, S. Albrecht, J. Radioanal. Nucl. Chem. Letters, 1987,117, 275.
• [51] R. Dreyer, I. Dreyer, S. Fischer, H. Hartmann, F. Rosch, J. Radioanal. Nucl. Chem. Letters, 1985, 96, 333.
• [52] S. Fischer, R. Dreyer, H. Husein, M. Weber, H. Hartmann, J. Radioanal. Nucl. Chem. Letters, 1987,119, 181.
• [53] R. Ludwig, R. Dreyer, S. Fischer, Radiochim. Acta, 1989, 47, 129.
• [54] R. Ludwig, S. Fischer, R. Dreyer, R. Jacobi, J. Beger, Polyhedron, 1991, 10, 11.
• [55] J. Beger, R. Jacobi, H. Merkwitz, K. Gloe, P. Muhl, Z. Chemie, 1984, 24, 230.
• [56] F. Dietze, K. Gloe, R. Jacobi, P. Muhl, J. Beger, M. Petrich, L. Beyer, E. Hoyer, Solv. Extract. Ion Exch., 1989, 7, 223.
• [57] R. Louis, F. Amaud-Neu, R. Weiss, M.J. Schwing-Weill, Inorg. Nucl. Chem. Lett., 1977,13,31.
• [58] L. Vasaros, Yu.V. Norseev, V.A. Khalkin, Dokl. Akad. Nauk SSSR, 1982, 266, 120.
• [59] L. Vasaros, Yu.V Norseev, D.D. Nhan, V.A. Khalkin, Radiochem. Radioanal. Lett., 1982,54, 239.
• [60] Yu.V. Norseev, L. Vasaros, D.D. Nhan, N.Q. Huan, Radiokhimiya, 1987, 29,474.
• [61] GJ. Meyer, K. Rossler, G. Stocklin, Radiochim. Acta, 1977, 24, 81.
• [62] G.W.M. Visser, E.L. Diemer, F.M. Kaspersen, J. Labbelled Compd Radiopharm., 1980, 17, 657.
• [63] G.W.M. Visser, E.L. Diemer, F.M. Kaspersen, J. Labbelled Compd Radiopharm., 1981, 18, 799.
• [64] G.W.M. Visser, E.L. Diemer, F.M. Kaspersen, Int. J. Appl. Rad. Isotop., 1980,31, 275.
• [65] G.W.M. Visser, E.L. Diemer, Int. J. Appl. Rad. Isotop., 1982, 33, 389.
• [66] R.A. Milius, W.H. McLaughlin, R.M. Lambrecht, A.P. Wolf, J.J. Carroll, S.J. Adelstein, W.D. Bloomer,, Int. J. Appl. Rad. Isotop., 1986,37, 799.
• [67] E.L. Johnson, Nucl. Med. Biol., 1995, 22,45.
• [68] L.J. Jardine, Phys. Rev. C, 1975, 2, 1385.
• [69] W. Whaling, Handbuch der Physik, Ed. by S. Flugge, Vol. 34,211, Springer-Verlag, Berlin 1985.
• [70] C. Lucke-Huhle, E.A. Blakely, P. Y. Chang, C. A. Tobias, Radiat. Res., 1979, 79, 97.
• [71] V. Bertsche, G. Iliakis, G. Kraft, Radiat. Res., 1983, 95, 57.
• [72] C. Lucke-Huhle, Radiat. Res., 1982, 89, 298.
• [73] M.A. Ritter, J.W. Cleaver, C.A. Tobias, Nature, 1977, 266, 653.
• [74] G. Kohler, C. Milstein, Nature, 1975, 256, 495.
• [75] M. Argentim, Federal Institute for Reactor Research, Annual Report, Wurenlingen Switzerland 1982, p. 319.
• [76] K. Berei, L. Vasaros, Astatine Compounds, Hungarian Academy of Sciences, Budapest, Report KFKI-1984-29,668.
• [77] A.M. Friedman, M.R. Zalutsky, W. Wung, F. Buckingham, P. Harper, E.H. Appclman, R. Rothberg, F.W. Fitch, F.P. Stuart, Int. J. Nucl. Med. Biol., 1977, 4, 219.
• [78] M.R. Zalutsky, P.K. Garg, H.S. Friedman, D.D. Bigner, Proc. Natl. Acad. USA, 1989, 86, 7149.
• [79] D.S. Wilbur, M.D. Hylarides, A.R. Fritzberg, Radiochim. Acta, 1989, 47, 137.
• [80] M.R. Zalutsky, N.S. Narula, Int. J. Appl. Rad. Isot., 1988, 39, 227.
• [81] S.W. Hadley, D.S. Wilbur, M.A. Gray, R.W. Archer, Bioconjugate Chem., 1991, 2, 171.
• [82] M.R. Zalutsky, D.D. Bigner, Acta Oncol., 1996, 35, 373.
• [83] R.H. Larsen, R.S. Bruland, P. Hoff, J. Alstad, T. Lindmo, E.K. Rofstad, Radiat. Res., 1994, 139, 178.
• [84] R.H. Larsen, R.S. Bruland, P. Hoff, J. Alstad, E.K. Rofstad, Br. J. Cancer, 1994, 69, 1000.
• [85] M. Farhanghi, R.A. Holmes, W.A. Volkert, K.W. Logan, A. Singh, J. Nucl. Med., 1992, 33, 1451.
• [86] H. Fleisch, Bisphosphonates in Borte Disease. From the Laboratory to the Patient, 2nd edition, The Partenon Publishing Group, New York 1995.
• [87] V.J. Lewington, Phys. Med. Biol., 1996, 41,2027.
• [88] R.H. Larsen, K.M. Murud, G. Akabani, P. Hoff, R.S. Bruland, M.R. Zalutsky, J. Nucl. Med., 1999, 40, 1197.
• [89] K.M. Murud, R.H. Larsen, P. Hoff, M.R. Zalutsky, Nucl. Med. Biol., 1999,26, 397.
• [90] G.W.M. Visser, E.L. Diemer, F.M. Kaspersen Int. J. Appl. Radiat. Isotop., 1979,30,749.
• [91] Yu. V. Norseev, D.D. Nhan, V.A. Khalkin, N.Q. Huan, L. Vasaros, J. Radioanal. Nucl. Chem. Letters, 1985, 94, 185.
• [92] I. Brown, R.N. Carpenter, E. Link, J.S. Mitchell, J. Radioanal. Nucl. Chem. Letters, 1986, 107, 337.
• [93] Yu. V. Norseeev, J. Radioanal. Nucl. Chem., 1998, 237, 155.
• [94] E.M. Link, I. Brown, R.N. Carpenter, J.S. Mitchell, Cancer Res., 1989,49,4332.
• [95] E.M. Link, R.N. Carpenter, Cancer Res., 1992, 52,4385.
• [96] E.M. Link, R.N. Carpenter, G. Hansen, Eur. J. Cancer, 1996,32A, 1240.
• [97] P. Labarre, J. Papon, M.F. Moreau, N. Moins, A. Veyre, J.C. Madelmont, Eur. J. Nucl. Med., 1999, 26,494.
• [98] K. Rossler, G.J. Meyer, G.J. Stocklin, J. Labbelled Compd Radiopharm., 1977,13, 271.
• [99] J. Koziorowski, R. Weinreich, J. Radioanal. Nucl. Chem., 1997,219, 127.
• [100] J. Koziorowski, O. Labeda, R.Weinreich, Appl. Radiat. Isotop., 1999,50, 527.