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Spectrophotometric methods of determination of nitrates (III), (V) and nitric oxides with the use of the Griess-Ilosvay reaction
Języki publikacji
Abstrakty
The paper presents a review of spectrophotometric methods for determination of nitrates (III), (V) and nitric oxides [1–48] with particular emphasis on the possibilities of the Griess–Ilosvay method. The original method [50, 51] developed for determination of nitrates (III) and based on derivatisation of these compounds to nitrogen dyes has undergone many modifications over the decades. The aim of the modifications was to enhance the method’s sensitivity, decrease the level of determination, simplify the procedure and its adjustment to achieve the most effective determination also in the presence of a complex matrix [52–67]. The increasing demands of analytical chemistry and the need to determine trace or ultratrace amounts of nitrates have prompted further improvement of the Griess–Ilosvay method by combining it with methods of analyte enrichment such as liquid–liquid–extraction [68–80] and liquid–solid extraction [81–94]. The recent need for routine determinations in the monitoring of the natural environment has led to the development of the fast flow–through – injection methods [95–127], making the analytical process more effective and convenient to use. One of the most recent achievements in analytical chemistry of nitrates (III) and (V) has been the development of optical sensors (optrodes) [128–132]. They are used in modified versions of the Griess–Ilosvay method and permit a direct and relatively easy determination of the contents of nitrates preserving a high sensitivity of the method. The paper gives a comparative review of the modifications of the Griess–Ilosvay method from the earliest to the most recent .
Wydawca
Czasopismo
Rocznik
Tom
Strony
1181--1208
Opis fizyczny
Bibliogr. 132 poz., tab., wykr.
Twórcy
autor
- Wydział Chemii, Zakład Chemii Analitycznej, Uniwersytet im. Adama Mickiewicza, ul. Grunwaldzka 6, 60–780 Poznań
autor
- Wydział Chemii, Zakład Chemii Analitycznej, Uniwersytet im. Adama Mickiewicza, ul. Grunwaldzka 6, 60–780 Poznań
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PL
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Bibliografia
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