Sililenowe kompleksy metali przejściowych

Maciejewski, H.

Artykuł - szczegóły

Tytuł artykułu

Sililenowe kompleksy metali przejściowych

Autorzy

Maciejewski H.

Wybrane pełne teksty z tego czasopisma

Identyfikatory

Warianty tytułu

Silylene transition metal complexes

Języki publikacji

Abstrakty

Major advance in organometallic chemistry in the last 15 years has been achieved in the area of silicometallics chemistry, based on silicon to metal multiple bonding and silicon with low coordination numbers. Research in this area has led to a discovery of fundamentally new classes of compounds, such as silylene, silene, silaimine, disilene or silacarbyne complexes. Many of these systems had been unknown prior to their synthesis, even as reactive intermediates. This paper provides a comprehensive review of the silylene transition metal complexes. The majority of metal - silylene complexes synthesised so far have required donor stabilisation via the addition of a Lewis base. The use of thermally stable bis(amino)silylenes as ligands has led to a synthesis of base-free, stable silylene metal complexes. The chemistry of these compounds is discussed under headings: types of silylene complexes, methods of their synthesis, structure and properties of TM silylene complexes and also their application to catalysis. Despite the fact that the stable silylene transition metal complexes have been known for less than a decade, the chemistry of these compounds has been comprehensively recognised.

Słowa kluczowe

chemia metaloorganiczna kompleks sililenowy kompleksy metali przejściowych

transition metal complexes

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Wiadomości Chemiczne

Rocznik

2002

Tom

[Z] 56, 11-12

Strony

953--981

Opis fizyczny

tab., wykr., bibliogr. 101 poz.

Twórcy

autor

Maciejewski H.

Zakład Chemii Metaloorganicznej, Wydział Chemii Uniwersytetu im. A.Mickiewicza, ul. Grunwaldzka 6, 60-780 Poznań

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Typ dokumentu

Bibliografia

Identyfikator YADDA

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