Solwatochromia i barwniki solwatochromowe

Wróblewska, E.K.; Soroka, J.A.; Soroka, K.B.

Artykuł - szczegóły

Tytuł artykułu

Solwatochromia i barwniki solwatochromowe

Autorzy

Wróblewska E.K. , Soroka J.A. , Soroka K.B.

Wybrane pełne teksty z tego czasopisma

Identyfikatory

Warianty tytułu

Solvatochromism and solvatochromic dyes

Języki publikacji

Abstrakty

The phenomenon of solvatochromism is presented, taking into account the constitution of solvatochromic dyes, the physical interpretation and mathematical description (models) of solute-solvent interaction. The discussion covers Onsager's early reactions field model and subseqent qualitative interpretation of the solvent effect on solute dipole moment change by Bayliss and McRea. Subsequently solvatochromic dyes were presented briefly as empirical polarity indicators with respect to other methods applied to this goal. Binary solvents mixtures polarity models were critically discussed, taking into account the conceptions of Langhals, Dawber, Bosh and Rosés and Skwierczyński and Connors. After this introduction Soroka's models were presented: the physicochemical V-B-HB model based on solute electronic structural changes in pure solvents and the SA-SAB-SB model of solvatochromism in binary solvent mixtures. Both models describe well the behaviour of many pure solvents, as well as the properties of a number of binary systems series including ones well known from textbooks. These models provide reliable support for advanced investigations and precise interpretation of molecular interactions in liquids.

Słowa kluczowe

solwatochromia model solwatochromii spektrometria UV-VIS barwniki solwatochromowe

solvatochromism spectrometry UV-VIS

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Wiadomości Chemiczne

Rocznik

2002

Tom

[Z] 56, 1-2

Strony

113--150

Opis fizyczny

Bibliogr. 151 poz., tab., wykr.

Twórcy

autor

Wróblewska E.K.

Politechnika Szczecińska, Wydział Technologii i Inżynierii Chemicznej Instytut Chemii i Podstaw Ochrony Środowiska. Zakład Analizy Instrumentalnej al. Piastów 42, 71-065 Szczecin

autor

Soroka J.A.

Politechnika Szczecińska, Wydział Technologii i Inżynierii Chemicznej Instytut Chemii i Podstaw Ochrony Środowiska. Zakład Analizy Instrumentalnej al. Piastów 42, 71-065 Szczecin

autor

Soroka K.B.

Politechnika Szczecińska, Wydział Technologii i Inżynierii Chemicznej Instytut Chemii i Podstaw Ochrony Środowiska. Zakład Analizy Instrumentalnej al. Piastów 42, 71-065 Szczecin

Politechnika Szczecińska, Wydział Technologii i Inżynierii Chemicznej Instytut Chemii i Podstaw Ochrony Środowiska. Zakład Analizy Instrumentalnej al. Piastów 42, 71-065 Szczecin

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