Wpływ temperatury redukcji na właściwości sorpcyjne i katalityczne naniesionych układów metalicznych

Karski, S.; Ludomirska, I.; Witońska, I.

Artykuł - szczegóły

Tytuł artykułu

Wpływ temperatury redukcji na właściwości sorpcyjne i katalityczne naniesionych układów metalicznych

Autorzy

Karski S. , Ludomirska I. , Witońska I.

Wybrane pełne teksty z tego czasopisma

Identyfikatory

Warianty tytułu

The influence of reduction temperature on the sorption and catalytical properties of supported metallic systems

Języki publikacji

Abstrakty

Supported noble metal catalysts are used in a large number of commercially important processes, including hydrogenation and dehydrogenation, naphtha reforming and automotive exhaust catalysis. It is a well-known fact that support influences the catalytic activity and the selectivity of the supported metal particles. The most striking effect is the so-called strong metal - support interaction (SMSI) in which a metal / support catalyst is reduced at a high temperature (773 K) and the metal loses, at least partially, its chemisorptive properties with respect to H2 and CO. This effect was first discovered by Tauster at al. on titania and then extended to other reducible supports. Several explanations have been given to account for the loss of chemisorptive and catalytic properties: the occurrence of an electronic effect with an electron transfer between the support and the metal particles, the formation of intermetallic compounds, and the decoration of the metal by support mobile species . Another model describing the metal - support interaction and based on theoretical calculations suggests that the electron density in small metal particles is shifted toward nearby cations of the support. Recently a new model has been proposed, in which the decrease in the activity of metal clusters can be ascribed to a decrease in the ionization potential of the metal particles which is directly induced by the Coulomb potential of the support .

Słowa kluczowe

układ metaliczny temperatura redukcji oddziaływanie metal-nośnik kataliza adsorpcja

metallic systems reduction temperature adsorption catalysis

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Wiadomości Chemiczne

Rocznik

2001

Tom

[Z] 55, 11-12

Strony

1005--1027

Opis fizyczny

wykr., bibliogr. 137 poz.

Twórcy

autor

Karski S.

Instytut Chemii Ogólnej i Ekologicznej Politechniki Łódzkiej ul. Żwirki 36, 90-924 Łódź

autor

Ludomirska I.

Instytut Chemii Ogólnej i Ekologicznej Politechniki Łódzkiej ul. Żwirki 36, 90-924 Łódź

autor

Witońska I.

Instytut Chemii Ogólnej i Ekologicznej Politechniki Łódzkiej ul. Żwirki 36, 90-924 Łódź

Instytut Chemii Ogólnej i Ekologicznej Politechniki Łódzkiej, ul. Żwirki 36, 90-924 Łódź

Bibliografia

[1] Y. Yazawa, H. Yoshida, N. Takagi, S. Komai, A. Satsuma, T. Hattori, J. CataL, 1999, 187, 15.
[2] SJ. Tauster, S.C. Fung, R.L. Garten, J. Am. Chem. Soc., 1978, 100, 170.
[3] S.J. Tauster, S.C. Fung, J. Catal., 1978, 55, 29.
[4] R.T.K. Baker, E.B. Prestridge, R.L. Garten, J. Catal., 1979, 56, 390.
[5] R.T.K. Baker, E.B. Prestridge, R.L. Garten, J. Catal., 1979, 59. 293.
[6] G.L. Haller, D.E. Resasco, Adv. Catal., 1989, 36, 173.
[7] J.P. Hindermann, GJ. Hutchings, A. Kiennemann, Catal. Rev. Sei. Eng., 1993, 35, 1.
[8] Y.J. Lin, D.E. Resasco, G.L. Haller, J. Chem. Soc. Faraday Trans., 1987, 83, 2091.
[9] J. Kowalski, G. van der Lee, V. Pronec, Appl. Catal., 1985, 19, 423.
[10] B.J. Kip, E.G.F. Hermans, R. Prins, Appl. Catal., 1985, 35, 423.
[11] T. Koerts, JJ. Welters, R.A. van Santen, J. Catal., 1992, 134, 1.
[12] T. Mori, Catal. Lett., 1990, 7, 151
[13] A.B. Boffa, A.T. Bell, G.A. Somoijai, J. Catal, 1993, 139, 602.
[14] M.A. Vannice, J. Catal., 1982, 74, 199.
[15] P. Meriaudeau, O.H. Ellestad, M. Dufaux, C. Naccache, J. Catal., 1982, 75, 243.
[16] K. Foger, J. Catal, 1982, 78, 406.
[17] D. Duprez, A. Miloudi, Studies in Surface Science in Catalysis, Elsevier, Amsterdam 1981, 179.
[18] M.D. Mitchell, M.A. Vannice, Ind. Eng. Che. Fundam., 1984, 23, 88.
[19] M.A. Vannice, C. Sudhakar, M. Freeman, J. Catal., 1987, 108, 97.
[20] T. Beutel, V. Siborov, B. Tesche, H. Knözinger, J. Catal., 1997,167, 379.
[21] K. Kunimori, T. Wakasugi, F. Yamakawa, H. Oyanagi, J. Nakamura, T. Uchijima, Catal. Lett., 1991,9, 331.
[22] G.A. Martin, J.A. Dalmon, React. Kinet. Catal. Lett., 1981,16, 325.
[23] Z. Hu, T. Wakasagi, A. Maeda, K. Kunimori, T. Uchijima, J. Catal., 1991, 127, 276
[24] Z. Hu, H. Nakamura, K. Kunimori, H. Asano, T. Uchijima, J. Catal, 1988, 112, 47.
[25] G.C. Bond, [w:] Metal-Support and Metal Additive Effect in Catalysts, Elsevier, Amsterdam 1983, s. 1.
[26] A.L. Yakovlev, G.M. Zhidomorov, K.M. Neyman, V.A. Nashozov, N. Rosch, Ber. Bunsenges Phys. Chem., 1996,100, 413.
[27] H. Onishi, T. Aruga, C. Egawa, Y. Iwasawa, Surf. Sei., 1982, 121, 303.
[28] J.M. Herrmann, P. Pichat, J. Catal, 1982, 78, 425.
[29] G.J. Den Otter, I.M. Dautzenberg, J. Catal., 1975, 37, 324.
[30] J. Adamiec, S.E. Wanke, B. Tesche, U. Klenger, [w:] Metal-Support and Metal Additive Effect in Catalysis, Elsevier, Amsterdam 1982, s. 77.
[31] S. Karski, Przemysł Chem., 1992, 71/5, 177.
[32] S. Fuentes, F. Figueras, J. Chem. Soc. Faraday Trans., 1978, 74, 174.
[33] R. Maurel, G. Leclercq, J. Barbier, J. Catal, 1975, 37, 324.
[34] SJ. Tauster, S.C. Fung, R.T.K. Baker, J.A. Horsley, Science, 1981, 211, 1121.
[35] F. Solymosi, L. Volgyesi, J. Sarkany, J. Catal, 1978, 54, 336.
[36] P.G. Menon, G.F. Froment, Appl. Catal, 1981, 1, 31.
[37] P.G. Menon, G.F. Froment, J. Catal., 1979, 59, 138.
[38] M.A. Vannice, J. Catal., 1982, 74, 199.
[39] M.A. Vannice, R.L. Garten, J. Catal., 1980, 63, 255.
[40] F. Solymosi, I. Tombacz, M. Kocsis, J. Catal., 1982, 75, 78.
[41] T.M. Apple, P. Gajardo, C. Dybowski, J. Catal., 1981, 68, 103.
[42] D. Resasco, G.L. Haller, J. Chem. Soc. Chem. Commun., 1980, 1150.
[43] S.Y. Wang, S.H. Moon, J. Catal., 1981, 71, 167.
[44] M.A. Vannice, S.Y. Wang, S.H. Moon, J. Catal., 1981, 71, 152.
[45] T.M. Apple, C. Dybowski, J. Catal., 1981, 71, 316.
[46] C.H. Bartholomew, R.B. Pannell, J.L. Butler, J. Catal., 1980, 65, 33.
[47] M.A. Vannice, R.L. Garten, J. Catal., 1979, 56, 236.
[48] D.G. Mustard, C.H. Bartholomew, J. Catal., 1981, 67, 186.
[49] K. Chen, Y. Fan, Q. Yan, J. Catal., 1997,167, 573
[50] L.M. Tau, C.O. Bennett, J. Catal., 1984, 89, 285.
[51] J. Santos, J. Phillips, J.A. Dumesic, J. Catal.. 1983, 81, 147.
[52] J.M. Thomas, P. L. Walker, J. Phys., 1964, 41, 587.
[53] SJ. Tauster, S.C. Fung, R.T.K. Baker, J.A. Horsley, J. Catal., 1978, 55, 29.
[54] C. Dall’Agnol, A. Gervasini, F. Morazzoni, F. Pinna, G. Strukul, L. Zanderighi, J. Catal., 1985, 96, 106.
[55] P. Meriaudeau, J.F. Dutel, M. Dufaux, C. Naccache, Stud. Surf. Sci. Catal., 1982,11, 95.
[56] J. Barrault, A. Alouche, V. Paul-Boncour, L. Hilaire, A. Percheron-Guegan, Appl. Catal., 1989, 46, 269.
[57] M. Guenin, P.N. Da Silva, R. Fretty, Appl. Catal., 1986, 27, 313.
[58] J. Cunningham, S. O’Brien, J. Sanz, J.M. Rojo, J.A. Soria, J.L.G. Fierro, J. Mol. Catal., 1990, 57, 379.
[59] A.K. Datye, D.S. Kalakkad, M.H. Yao, D.J. Smith, J. Catal., 1995, 155, 148.
[60] M.A. Vannice, L.C. Hasselbring, B. Sen, J. Catal., 1985, 95, 57.
[61] M.A. Vannice, L.C. Hasselbring, B. Sen, J. Phys. Chem., 1985, 89, 2972.
[62] E.J. Braunschweig, A.D. Logan, A.K. Datye, D.J. Smith, J. Catal., 1989.118,227.
[63] S. Bemal, J.J. Calvino, M.A. Cauqui, G.A. Cifredo, A. Jobacho, J.M. Rodríguez-Izquierdo, Appl. Catal., 1993, 99, 1.
[64] R.W. McCabe, R.K. Usmen, K. Ober, H.S. Gandhi, J. Catal., 1995, 151, 385.
[65] L. Wang, G.W. Qiao, H.Q. He, K.H. Quo, Y.X. Chen, Proceedings, 9th International Congress Catalysis, Calgary 1988.
[66] J.G. Santiesteban, D.C. Calabro, W.S. Borghard, C.D. Chang, J.C. Vartuli, Y.P. Tsao, M.A. Natal-Santiago, R.D. Bastían, J. Catal, 1999, 183, 314.
[67] J.H. Bitter, K. Seshan, J.A. Lercher, J. Catal., 1997,171, 279.
[68] J. Goetz, M.A. Volpe, A.M. Sica, C.E. Gigola, R. Tourouda, J. Catal., 1997,167, 314.
[69] T. loannides, M. Tsapatsis, M. Koussathana, X.E. Veiykios, J. Catal., 1995,152, 331.
[70] D. Briggs, J. Dewing, A.G. Burden, R.B. Moyes, P.H. Wells, J. Catal., 1980, 65, 31.
[71] F. Coloma, J.M. Coronado, C.H. Rochester, J.A. Anderson, Catal. Lett., 1998, 51, 155.
[72] F. Coloma, A. Sepulveda-Escribano, J.L.G. Fierro, F. Rodriguez-Reinoso, Appl. Catal., 1997, 150, 165.
[73] A. Dandekar, M.A. Vannice, J. Catal., 1999,183, 344.
[74] F.I. Ko, R.L. Garten, J. Catal., 1981, 68, 233.
[75] M.A.Vannice, P. Chon, 8th Intern. Congr. Catal., Berlin, 1984, 5, 99.
[76] R. Burch, A.R. Flambard, React. Kinet. Catal. Lett., 1981,17, 23.
[77] A. Gampine, D.P. Eyman, J. Catal., 1998,179, 315.
[78] S. Karski, S. Wanke, 10th Canadian Symposium of Catalysis, Kingston, Ontario 1986.
[79] L. Fan, K. Fujimoto, J. Catal., 1994,150, 217.
[80] R. Burch, A.R. Flambard, J. Catal., 1982, 78, 389.
[81] Y.A. Ryndin, R.F. Hicks, A.T. Bell, Y.I. Yermakov, J. Catak, 1981, 70, 287.
[82] C. de Leitenburg, A. Trovarelli, J. Catak, 1995, 156, 171.
[83] S. Bernal, J.J. Calvino, M.A. Cauqui, G.A. Cifredo, A. Jobacho, J.M. Rodríguez-Izquierdo, Appl. Catak, 1993, 99, 1.
[84] A. Trovarelli, G. Dolcetti, C. de Leitenburg, J. Kaspar, R Finetti, A. Santoni, J. Chem. Soc. Faraday Trans., 1992, 88 , 1311.
[85] S. Bernal, FJ. Botana, JJ. Calvino, M.A. Cauqui, J.M. Pintado, J.M. Rodríguez-Izquierdo, J. Phys. Chem., 1993, 97, 4118.
[86] J. Cunningham, C. O’Brian, J. Sanz, J.M. Rojo, J.A. Soria, J.G.L. Fierro, J. Mol. Catak, 1990, 57, 379.
[87] L. Bruce, J.F. Mathews, Appl. Catak, 1982, 4, 353.
[88] C.D. Dall’Agnol, A. Gervasini, F. Morazzoni, F. Pinna, F. Strukuł, J. Catak, 1985, 96, 106.
[89] H. Yoshitake, Y. Iwazawa, J. Phys. Chem., 1992, 96, 1329.
[90] K. Asakura, Y. Iwazawa, S. Purnell, B. Watson, M. Barteau, B.C. Gates, Catak Lett., 1992, 15, 307.
[91] B. Coq, P.S. Kumbhar, C. Moreau, P. Moreau, F. Figuras, J. Phys. Chem., 1994, 98, 10180.
[92] R. Szymański, H. Charcosset, P. Gallezot, P. Massardier, L. Toumayan, J. Catak, 1986, 97, 366.
[93] C.C. Kao, S.C. Tsai, Y.W. Chung, J. Catak, 1982, 73, 136.
[94] E. Ruckenstein, H.Y. Wang, J. Catak, 1999,187, 151.
[95] Z.L. Zhang, V.A. Tsipouriari, A.M. Efstathiou, X.E. Verykios, J. Catak, 1996, 158, 51.
[96] J. Nakamura, K. Aikawa, K. Sato, T. Uchijima, Catak Lett., 1994, 25, 265.
[97] A. Erdohelyi, J. Cresenyi, F. Solymosi, J. Catak, 1993,141, 287.
[98] J.G. Santiesteban, D.C. Calabro, W.S. Borghard, C.D. Chang, J.C. Vartuli, Y.P. Tsao, M.A. Natal-Santiago, R.D. Bastían, J. Catak, 1999,183, 314.
[99] G. Larsen, G.L. Haller, Catak Lett., 1989, 3, 103.
[100] A. De Mallmann, D. Barthomeuf, J. Chim. Phys., 1990, 87, 535.
[101] M. Sugimoto, H. Katsuno, T. Hayasaka, N. Ishikawa, K. Hirasawa, Appl. Catak, 1993, 102, 167.
[102] J.H. Sinfelt, Catak Rev., 1969, 3, 175.
[103] S.D. Worley, C.A. Rice, G.A. Mattson, C.W. Curtis, J.A. Guin, A.R. Tarrer, J. Phys. Chem., 1982, 86, 2714.
[104] T. Huizinga, R. Prins, J. Phys. Chem., 1981, 85, 2156.
[105] T. Iwaki, K. Katsuta, M. Maira, J. Catak, 1981, 68, 492.
[106] J.A. Horsley, J. Amer. Chem. Soc., 1979,101, 2870.
[107] C.C. Kao, S.C. Tsai, M.K. Bahl, Y.W. Chung, W.J. Lo, Surf. Sci., 1980, 95, 1.
[108] R. Burch, A.R. Flambard, Studies in Surface Science and Catalysis, Elsevier, Amsterdam 1982, s. 193.
[109] J.M. Hermann, J. Catak, 1989, 118, 43.
[110] A.P.J. Jansen, R.A. van Santen, J. Phys. Chem., 1990, 94, 6764.
[111] E. Sanchez-Marcos, A.P.J. Jansen, R.A. van Santen, Chem. Phys. Lett., 1990, 167, 399.
[112] H. Yoshitake, Y. Iwasawa, J. Phys. Chem., 1992, 96, 1329.
[113] G.B. Raupp, J.A. Dumesic, J. Catak, 1985, 95, 1985.
[114] G.B. Raupp, J.A. Dumesic, J. Phys. Chem., 1984, 88, 660.
[115] J.D. Bracey, R. Burch, J. Catak, 1984, 86 , 384.
[116] E.C. Akubuiro, X.E. Verykios, J. Catak, 1987, 103, 320.
[117] E.C. Akubuiro, X.E. Verykios, J. Catak, 1988, 113, 106.
[118] E.C. Akubuiro, X.E. Verykios, J. Phys. Chem. Solids, 1989, 50, 17.
[119] E.C. Akubuiro, T. Ioannides, X.E. Verykios, J. Catak, 1989, 116, 590.
[120] E.C. Akubuiro, X.E. Verykios, T. Ioannides, Appl. Catak, 1989, 46, 297.
[121] T. Ioannides, X.E. Verykios, J. Catal., 1994,145, 479.
[122] Z. Zhang, A. Kladi, X.E. Verykios, J. Catal., 1994, 148, 737.
[123] F. Solymosi, I. Tombacz, J. Koszta, J. Catal., 1985, 95, 578.
[124] H. Yoshitake, Y. Iwasawa, J. Phys. Chem., 1992, 96, 1329.
[125] B.L. Mojet, J.T. Miller, D.E. Ramaker, D.C. Koningsberger, J. Catal., 1999, 186, 373.
[126] V. Pitchon, M. Guenin, H. Praliaud, Appl. Catal., 1990, 63, 333.
[127] G.J. Blyholder, J. Phys. Chem., 1964, 68, 2772.
[128] Z. Karpiński, S.N. Gandhi, W.H.M. Sachtler J. Catal., 1993,141, 337.
[129] S.T. Homeyer, Z. Karpiński, W.M.H. Sachtler, J. Catal., 1990,123, 137.
[130] G. Larsen, G.L. Haller, Catal. Lett., 1989, 3, 103.
[131] A. de Mallmann, D. Barthomeuf, J. Chim., Phys. 1990, 87, 535.
[132] M. Sugimoto, H. Katsuno, T. Hayasaka, N. Ishikawa, K. Hirasawa, Appl. Catal., 1993.102, 167.
[133] S.J. Tauster, Acc. Chem. Res., 1987, 20, 398.
[134] J.R. Katzer, A.W. Sleight, P. Gajaro, J.B. Michel, E.F. Gleason, S. McMillan, Faraday Discussion, Nottingham, 1981, s. 8.
[135] J.M. Driessen, E.K. Poels, J.P. Hinderman, V. Ponec, J. Catal., 1983, 82, 26.
[136] C.S. Co, R.J. Gorte, J. Catal., 1984, 90, 59.
[137] A.J. Simoens, R.T.K. Baker, D.J. Dwyer, C.R.F. Lund, R.J. Madon, J Catal., 1984, 86, 359.

Uwagi

Opracowane ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUS1-0010-0044