Swobodna energia międzyfazowa a swobodna energia adsorpcji i micelizacji substancji powierzchniowo czynnych

• Autorzy: Jańczuk B. , Wójcik W. , Zdziennicka A. , Gonzalez-Martin M.A. , Bruque J.M.

Warianty tytułu

EN

Interfacial free energy and free energy of adsorption and micellization of surface active agents

• Języki publikacji: PL

Abstrakty

EN

This paper reviews the results of investigations of the surface free energy of surfactants and the correlation between hydrophobic group of surfactant-water and hydrophilic group of surfactant-water interfacial free energy and standard free energy of adsorption at water-air (oil) interface and standard free energy of micellization. The surface free energy of the hydrophobic and hydrophilic group of the surfactants is considered separately. The van Oss and co-workers' approach to the interfacial liquid-liquid and solid-liquid free energy used for the energy determination has been described. This approach treats the surface free energy of a solid and a liquid as the sum of the Lfshitz-van der Waals and Lewis acid-base components. The acid-base component of the surface free energy depends on the electron-acceptor and electron-donor parameters of this energy. Different determination ways of the surface free energy components and parameters of the hydrophobic and hydrophilic group of the surfactants are shown. The usefulness of the Young equation and adsorption data of n-alkanes on solid surface for determination of the Lifshitz-van der Waals component and electron-acceptor parameters of the acid-base component of the hydrophilic group of the surfactants is presented. On the basis of the surface free energy components and parameters of the hydrophobic and hydrophilic group of the surfactants and recently modified DLVO theory, the free energy of interaction between molecules or ions of the surfactants through the water phase and the free energy of removing surfactant molecules or ions from the water phase to air or oil phase can be predicted. The modified DLVO theory treats the interaction between molecules or particles through the liquid phase as the sum of Lifshitz-van der Waals, acid-base and electrostatic interaction components, which details are described for the systems including ionic or nonionic surfactants. The free energy of interaction can be used for prediction of the standard free energy of adsorption and micellization of the surfactants if the contactable area of the molecules or ions of the surfactants is known. Different ways of the contactable area between the hydrophobic and hydrophilic group of the surfactants and between groups and water molecules are presented. The calculated values of the free energy of interactions of the surfactants through water phase are compared to the standard free energy of micellization and the standard free energy of the adsorption of surfactants at water-air (oil) interface. For this purpose the determination of the standard free energy of adsorption from isotherms of adsorption of the surfactants and their standard free energy of micellization is also described.

Słowa kluczowe

PL

adsorpcja; energia swobodna adsorpcji; micelizacja; energia swobodna micelizacji; energia swobodna powierzchniowa surfaktanów

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Wiadomości Chemiczne
• Rocznik: 2000
• Tom: [Z] 54, 9-10
• Strony: 793--815
• Opis fizyczny: bibliogr. 69 poz.

Twórcy

autor

Jańczuk B.

• Zakład Zjawisk Międzyfazowych Wydziału Chemii UMCS w Lublinie pl. Marii Curie-Skłodowskiej 3, 20-031 Lublin

autor

Wójcik W.

• Zakład Zjawisk Międzyfazowych Wydziału Chemii UMCS w Lublinie pl. Marii Curie-Skłodowskiej 3, 20-031 Lublin

autor

Zdziennicka A.

• Zakład Zjawisk Międzyfazowych Wydziału Chemii UMCS w Lublinie pl. Marii Curie-Skłodowskiej 3, 20-031 Lublin

autor

Gonzalez-Martin M.A.

• Departamento de Física, Universidad de Extremadura Avda. De Elvas sfn, 06071 Badajoz, España

autor

Bruque J.M.

• Departamento de Física, Universidad de Extremadura Avda. De Elvas sfn, 06071 Badajoz, España

• Zakład Zjawisk Międzyfazowych Wydziału Chemii UMCS w Lublinie pl. Marii Curie-Skłodowskiej 3, 20-031 Lublin

Bibliografia

• [1] C. J. van Oss, R. J. Good, J. Dispersion Sci. Technol., 1991, 12, 95.
• [2] C. J. van Oss, P. M. Constanzo, J. Adhesion Sci. Technol., 1992, 6, 477.
• [3] B. Jańczuk, J. M. Bruque, M. L. Gonzalez-Martin, E. Roman-Galan, Colloids Surf., 1995, 100, 93.
• [4] B. Jańczuk, M. L. Gonzalez-Martln, J M Bruque, C. Dorado-Calasanz, J. Moreno del Pozo, J. Colloid Interface Sci., 1995, 176, 352.
• [5] B. Jańczuk, J. A. Mendez-Sierra, M. L. Gonzalez-Martln, J. M. Bruque, W Wójcik, ibid., 1996, 184, o07
• [6] B. Jańczuk, J. A. Mendez-Sierra, M. L. Gonzalez-Martln, J. M. Bruque, W. Wójcik, ibid., 1997, 192, 408.
• [7] B. Jańczuk, A. Zdziennicka, K. Jurkiewicz, W. Wojcik, Tenside Surf. Deter., 1998,35, 213.
• [8] B. Jańczuk, A. Zdziennicka, W. Wójcik, w druku.
• [9] A. W. Neumann, Z. Phys. Chem (Leipzig), 1964, 187, 227.
• [10] C. A. Ward, A. W. Neumann, J. Colloid Interface Sci., 1974, 49, 286.
• [11] O. Driedger, A. W. Neumann, P. J. Seel, Colloid-Z. Z. Polym.. 1965, 201, 52.
• [12] A. W. Neumann, R. J. Good, C. J. Hope, M. Sejpol, J. Colloid Interface Sci., 1974, 49, 291.
• [13] A. W. Neumann, Adv. Colloid Interface Sci., 1974, 4. 105.
• [14] D. Li, A. W. Neumann, ibid., 1992, 39, 299.
• [15] D. Li, A. W. Neumann, J. Colloid Interface Sci., 1990, 137, 304.
• [16] F. M. Fowkes, J. Phys. Chem., 1962, 66, 382.
• [17] F. M. Fowkes, Ind. Eng. Chem., 1964, 56/12, 40.
• [18] F. M. Fowkes, J. Phys. Cham , 1968, 72, 3700.
• [19] F. M. Fowkes, J. Adhesion, 1972, 4, 153.
• [20] D. K. Owens, R. C. Wendt, J. Appl. Polym. Sci., 1969, 13, 1741.
• [21] D. H. Kaelble, G Uy, J. Adhesion, 1970, 2, 50.
• [22] D. H. Kaelble, E. H. Cirlin, J. Polymer Sci., 1971, 9, 363.
• [23] D. H. Kaelble, J. Adhesion, 1970, 2, 68.
• [24] Y. Kitazaki, T. Hata, ibid., 1972, 4, 123.
• [25] S. Wu, J Phys. Chem., 1970, 74, 632.
• [26] S. Wu, ibid., 1968, 72, 3332.
• [27] S. Wu, [w:] Polymer Blends, Vol. 1, D. R. Paul, S. Neumann, (eds.), Academic Press, New York 1978, 243-293.
• [28] J. Kloubek, Collect. Czech. Chem. Commun., 1991, 56, 227.
• [29] J. Kloubek, Langmuir, 1989, 5, 1127.
• [30] C. J. van Oss, R. J. Good, J. Macromol. Sci.-Chem., 1989, A26, 1183.
• [31] M. K. Chaudhury, Short-Range and Long-Range Forces in Colloid and Macroscopic Systems, Ph. D. Thesis, State University of New York at Buffalo, New York 1984.
• [32] C. J. van Oss, R. J. Good, M. K. Chaudhury, J. Colloid Interface Sci., 1986. Ill, 378.
• [33] C. J. van Oss, M. K. Chaudhury, R. J. Good, Chem. Rev., 1988, 88, 927.
• [34] R. J. Good, C. J. van Oss, [w:] Modern Approach to Wettability: Theory and Applications, M. E. Schrader, G. Loeb (eds.), Plenum Press, New Yorl 1991, 1.
• [35] C. J. van Oss, Interfacial Forces in Aqueous Media, Dekker, New York 1994.
• [36] W. B. Jensen, The Lewis Acid-Base Concept, Wiley-Interscience, New York 1980.
• [37] W. B. Jensen, The Relevance of Lewis Acid-Base Chemistry to Surface Interactions, [w:] Surface and Colloid Science in Computer Technology, K. L. Mittal (ed.) Plenum Press, New York 1987.
• [38] P. A. Smali, J. Appl. Chem., 1953, 3, 71.
• [39] P. Kollmann, J. McKelvey, a. Johannson, S. Rothenberg, J. Am. Chem . Soc., 1975, 5, 955.
• [40] P. Kollmann, J. Am. Chem. Soc., 1977, 99, 4875.
• [41] D. Berthelot, Compt. Read. 1898, 126, 1703, 1857.
• [42] B. Jańczuk, W. Wójcik, A. Zdziennicka, J. Colloid Interface Sci., 1993, 157, 384.
• [43] A. W. Adamson, Physical Chemistry of Surface, 5,h Ed., Wiley-mterscience, New York 1991.
• [44] A. B. D. Cassie, S Baxter, Trans. Faraday Soc., 1944, 40, 546.
• [45] A. B. D. Cassie, Disc. Faraday Soc., 1948, 3, 11.
• [46] K. Tajima, M. Muramatsu, T. Sasaki, Bull. Chem. Soc. Japan, 1970, 43, 1991.
• [47] D. K. Chat a raj, K. S. Birdi, Adsorption and Gibbs Surface Excess. Plenum Press, New York 1984.
• [48] M. J. Rosen, Surfactants and Interfaces Phenomena, 2nd Ed., Wiley-Interscience, 1989
• [49] M. J. Jaycock, G. G. Parffit, Chemistry of lnterfaces, Ellis Horwood, Chichester 1981.
• [50] J. H. De Bo er, The Dynamic Character of Adsorption, Oxford University Press, Oxford 1953.
• [51] M. J. Rosen, S. Aronson, Colloids Surf, 1981, 3, 201.
• [52] B. Jańczuk, M. L. Gonzalez-Martin, J. M. Bruque, C. Dorado-Calasanz, Tenside Surf. Deter., 1996, 33, 379.
• [53] B. Jańczuk, J. M. Bruque, M. L. Gonzalez-Martin, C. Dorado-Calasanz, Langmuir, 1995, 11, 4515.
• [54] B. Jańczuk, M. L. Gonzalez-Martin, J. M. Bruque, C. Dorado-Calasanz, Colloids Surf., 1998, 137, 15.
• [55] M. J. Hey, J. W. MacTaggart, C. H. Rochester, J. Chem. Soc. Faraday Trans. 1, 1984, 699, 80.
• [56] F. M. Fowkes, [w:] Hydrophobic Surfaces, F. M. Fowkes (ed.), Academic Press, New York/London 1969, 151.
• [57] P. Murkejee, Adv. Colloid Interface Sci., 1967, 1, 241.
• [58] G. Stainsby, A. E. Alexander, Trans. Faraday Soc., 1950, 46, 587.
• [59] E Matijevic, B. A. Pethica ibid., 1958, 54, 587.
• [60] B. W. Barry, G. F. J. Russel, J. Colloid Interface Sci., 1972, 40, 174.
• [61] N. M. van Os, G. J. Daane, T. A. B. M. Bolsman, ibid., 1987, 115, 402.
• [62] C. J. van Oss, R. E. Giese, P. M. Constanzo, Clays Clay Miner., 1990, 38, 151.
• [63] C. J. van Oss, R. J. Good, M. K. Chaudhury, J. Chromatogr., 1987, 391, 53.
• [64] C. J. van Oss, R. J. Good, H. J. Busscher, J. Dispersion Sci. Technol., 1990, 11, 75.
• [65] A. Kitahara, A. Watanabe, Electrical Phenomena at Interfaces, [w:] Surfactant Science Series, Vol. 15, A. Kitahara, A. Watande (Eds.), Marcel Dekker Inc., New York 1984.
• [66] R. S. Snyder, M. Bier, R. N. Griffin, A. J. Johnson, H. Leidheiser, Jr., F. J. Micale, J. W. Vanderhoff, S. Ross, C. J. van Oss, Sep. Purif. Methods, 1973, 2, 259.
• [67] J. T. Davies, J. Colloid Sci., 1956, 11, 3Ti.
• [68] A. J. Groszek, Proc. R. Soc. London Ser. A, 1970, 314, 473.
• [69] A. Nakagaki, T. Masayuki, Bull. Chem. Soc. Japan, 1983, 56, 2548.

Uwagi

PL

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).