O metodach syntezy polieterów z monometrów oksiranowych

Stolarzewicz, A.; Neugebauer, D.

Artykuł - szczegóły

Tytuł artykułu

O metodach syntezy polieterów z monometrów oksiranowych

Autorzy

Stolarzewicz A. , Neugebauer D.

Wybrane pełne teksty z tego czasopisma

Identyfikatory

Warianty tytułu

Methods for the synthesis of polyethers from oxirane monomers

Języki publikacji

Abstrakty

Methods of the oxiranes polymerization and the influence of the process conditions on the structure and properties of polyethers obtained are discussed. There are presented new methods for the synthesis of polyethers with hydroxyl end groups. In one of them double metal cyanide (DMC) complexes are used for the polymerization of propylene oxide and other oxiranes. The high activity is shown by a system containing Zn3(Co(CN) 6) 2 with the addition of zinc chloride, dimethoxyethane and water. Diols and triols with Mn up to 10 000, and with a very low amount of the monol fraction are obtained from propylene oxide. Potassium hydride and a crown ether are applied as the anionic initiator system in another method. Polymers of propylene oxide are formed in this case with Mn within the range between 6 000 and 12 000. They are mainly diols and they also contain the monol fraction. The chain transfer reaction to the monomer does not occur or its rate is strongly limited in the polymerization of some other oxiranes by potassium hydride. It allows to obtain the molecular weight of polyethers higher than that in the presence of the anionic initiators known so far. The Mn = 39 000 is found for example for poly(butylene oxide).

Słowa kluczowe

metoda syntezy polietery

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Wiadomości Chemiczne

Rocznik

2000

Tom

[Z] 54, 1-2

Strony

127--138

Opis fizyczny

wykr., bibliogr. 86 poz.

Twórcy

autor

Stolarzewicz A.

Centrum Chemii Polimerów Polskiej Akademii Nauk ul. M. Curie-Skłodowskiej 34, 41-819 Zabrze

autor

Neugebauer D.

Centrum Chemii Polimerów Polskiej Akademii Nauk ul. M. Curie-Skłodowskiej 34, 41-819 Zabrze

Centrum Chemii Polimerów Polskiej Akademii Nauk ul. M.Curie-Skłodowskiej 34, 41-819 Zabrze

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Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).

Typ dokumentu

Bibliografia

Identyfikator YADDA

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