Dibenzotetraaza[14]annuleny. Cz.1.

• Autorzy: Eilmes Julita , Ptaszek Marcin

Warianty tytułu

EN

Dibenzotetraaza[14]annulenes. Pt.1.

• Języki publikacji: PL

Abstrakty

EN

The title dibenzotetraaza[14]annulenes belong to the class of the synthetic tetraaza macrocyclic ligands of bioinorganic relevance. Their similarity to porphyrins makes them attractive as models of important biological systems like for example hemoproteins (hemoglobin, myoglobin), cytochromes and metalloenzymes (e.g. oxygenses, peroxidases, catalase). Dibenzotetraaza[14]annulene and porphyrin ligand both have four coplanar nitrogen donor atoms and substantial bond unsaturation and delocalization in the macrocyclic framework. However, the dibenzotetraaza[14]annulenes are Hückel anti-aromatic (4n), whereas the porphyrins are fully delocalized aromatic (4n+2). There is also remarkable difference in the confoormation of the macrocyclic ligand which is flat in porphyrins and taa system (R1=R3=H) and saddle-shaped in the case of other dibenzotetraaza[14]annulenes (R1=R3?H). The conformation of the ligands greatly influences the metal coordination geometries in their metal complexes. Structure of the dibenzotetraaza[14]annulenes is discussed in details in part II. The purpose of this article is to provide the readers with the preparative methods of the synthesis of various dibenzatetraaza[14]annulenes. Reactivity of the macrocyclic framework is also reviewed, as a method of further modification of the ligand structure. (...)

Słowa kluczowe

PL

układ makrocykliczny; dibenzotetraaza[14]annuleny; metoda syntezy; reaktywność

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Wiadomości Chemiczne
• Rocznik: 1999
• Tom: [Z] 53, 5-6
• Strony: 306--328
• Opis fizyczny: schem., bibliogr. 64 poz.

Twórcy

autor

Eilmes Julita

• Zakład Chemii Organicznej, Wydział Chemii, Uniwersytet Jagielloński ul. Ingardena 3, 30-060 Kraków

autor

Ptaszek Marcin

• Zakład Chemii Organicznej, Wydział Chemii, Uniwersytet Jagielloński ul. Ingardena 3, 30-060 Kraków

• Zakład Chemii Organicznej, Wydział Chemii, Uniwersytet Jagielloński, ul. Ingardena 3, 30-060 Kraków,

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