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Ortho-positronium migration in mesopores of MCM-41, MSF and SBA-3

Treść / Zawartość
Identyfikatory
Warianty tytułu
Konferencja
Proceedings of the 40th Polish Seminar on Positron Annihilation PSPA'2012, 13-14 June 2012, Kazimierz Dolny, Poland
Języki publikacji
EN
Abstrakty
EN
Three materials: MCM-41, MSF and SBA-3 with a very similar pore diameter but different lengths of cylindrical pores were investigated using the nitrogen sorption method and positron annihilation lifetime spectroscopy. The size of primary pores and interparticle spaces obtained by both methods is similar. However, volume ratios between the discussed kinds of pores found by the above-mentioned methods differ significantly. Such discrepancy is the result of both ortho-positronium migration and the inaccessibility of the pores for nitrogen. Comparing the results of nitrogen sorption and positron annihilation lifetime spectroscopy allows us to estimate that connectivity between the primary pores and the interparticle spaces is the highest in MCM-41 and lowest in SBA-3.
Czasopismo
Rocznik
Strony
235--240
Opis fizyczny
BIbliogr. 30 poz., rys.
Twórcy
autor
autor
  • Maria Curie-Skłodowska University, Institute of Physics, Department of Nuclear Methods, 1 M. Curie-Skłodowskiej Sq., 20-031 Lublin, Poland, Tel.: +48 81 537 6225, Fax: +48 81 537 6191, radek@zaleski.umcs.pl
Bibliografia
  • 1. Barrett EP, Joyner LG, Halenda PP (1951) The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms. J Am Chem Soc 73;1:373–380
  • 2. Chen F, Xu X-J, Shen S, Kawi S, Hidajat K (2004) Microporosity of SBA-3 mesoporous molecular sieves. Microporous Mesoporous Mater 75;3:231–235
  • 3. Ciesielski K, Dawidowicz AL, Goworek T, Jasińska B, Wawryszczuk J (1998) Positronium lifetimes in porous Vycor glass. Chem Phys Lett 289;1/2:41–45
  • 4. Fischer CG, Weber MH, Wang CL, McNeil SP, Lynn KG (2005) Positronium in low temperature mesoporous films. Phys Rev B 71;18:180102
  • 5. Gidley DW, Frieze WE, Dull TL et al. (2000) Determination of pore-size distribution in low-dielectric thin films. Appl Phys Lett 76;10:1282–1284
  • 6. Goldanskii V, Mokrushin A, Tatur A, Shantarovich V (1975) Positronium interactions with gases in pores of silicagels. Appl Phys A 5;4:379–382
  • 7. Grün M, Unger KK, Matsumoto A, Tsutsumi K (1997) Ordered mesoporous MCM-41 adsorbents: novel routes in synthesis, product, characterization and specification. In: McEnaney B, Mays JT, Rouquerol J, Rodriguez-Reinoso F, Sing KSW, Unger KK (eds) Characterisation of porous solids IV. Royal Society of Chemistry, Cambridge, p 81
  • 8. He C, Suzuki R, Ohdaira T et al. (2007) Study of mesoporous silica films by positron annihilation based on a slow positron beam: Effects of preparation conditions on pore size and open porosity. Chem Phys 331;2/3:213–218
  • 9. Huo Q, Margolese DI, Stucky GD (1996) Surfactant control of phases in the synthesis of mesoporous silica-based materials. Chem Mater 8;5:1147–1160
  • 10. Huo Q, Zhao D, Feng J et al. (1997) Room temperature growth of mesoporous silica fibers: A new high-surface-area optical waveguide (abstract). ChemInform 28:48
  • 11. Kullmann J, Enke D, Thraenert S, Krause-Rehberg R, Inayat A (2010) Characterization of nanoporous monoliths using nitrogen adsorption and positronium annihilation lifetime spectroscopy. Colloids Surf A 357;1/3:17–20
  • 12. Kunishige S, Koshimizu M, Asai K (2009) Temperature dependence of positron lifetime in ordered porous silica (SBA-3). Radiat Phys Chem 78;12:1088–1091
  • 13. Marlow F, Kleitz F (2001) Mesoporous silica fibers: internal structure and formation. Microporous Mesoporous Mater 44/45:671–677
  • 14. Marlow F, McGehee MD, Zhao D, Chmelka BF, Stucky GD (1999) Doped mesoporous silica fibers: A new laser material. Adv Mater 11;8:632–636
  • 15. Petkov MP, Wang CL, Weber MH, Lynn KG, Rodbell KP (2003) Positron annihilation techniques suited for porosity characterization of thin films. J Phys Chem B 107;12:2725–2734
  • 16. Shukla A, Peter M, Hoffmann L (1993) Analysis of positron lifetime spectra using quantified maximum entropy and a general linear filter. Nucl Instrum Methods Phys Res A 335;1/2:310–317
  • 17. Sing KSW, Everett DH, Moscou RAWL, Pierotti RA, Rouquerol J, Siemieniewska T (1985) Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984). Pure Appl Chem 57;4:603–619
  • 18. Thraenert S, Hassan EM, Enke D, Fuerst D, Krause-Rehberg R (2007) Verifying the RTE model: ortho-positronium lifetime measurement on controlled pore glasses. Phys Status Solidi C 4;10:3819–3822
  • 19. Ustinov EA, Do DD, Jaroniec M (2005) Adsorption of argon and nitrogen in cylindrical pores of MCM-41 materials: application of density functional theory. Appl Surf Sci 252;4:1013–1028
  • 20. Wang CL, Weber MH, Lynn KG, Rodbell KP (2002) Nanometer-scale pores in low-k dielectric films probed by positron annihilation lifetime spectroscopy. Appl Phys Lett 81;23:4413–4415
  • 21. Wilkinson NJ, Alam MA, Clayton JM, Evans R, Fretwell HM, Usmar SG (1992) Positron annihilation study of capillary condensation of nitrogen gas in a mesoporous solid. Phys Rev Lett 69;24:3535–3538
  • 22. Xi-Jie D, Yi-Fan H, Yu-Ying W (2010) Positronium diffusion in porous methylsilsesquioxane thin films. Chin Phys B 19;1:013601
  • 23. Zaleski R, Dolecki W, Kierys A, Goworek J (2012) n-Heptane adsorption and desorption on porous silica observed by positron annihilation lifetime spectroscopy. Microporous Mesoporous Mater 154:142–147
  • 24. Zaleski R, Goworek J, Borówka A, Kierys A, Wiśniewski M (2009) Positron porosimetry study of mechanical stability of ordered mesoporous materials. In: Seaton N, Reinoso FR, Llewellyn P, Kaskel S (eds) Characterisation of porous solids VIII. RSC Publishing, Cambridge, pp 400–407
  • 25. Zaleski R, Goworek J, Maciejewska M (2009) Positronium lifetime in porous VP-DVB copolymer. Phys Status Solidi C 6;11:2445–2447
  • 26. Zaleski R, Kierys A, Dziadosz M, Goworek J, Halasz I (2012) Positron annihilation and N2 adsorption for nanopore determination in silica-polymer composites. RSC Advances 2;9:3729–3734
  • 27. Zaleski R, Kierys A, Grochowicz M, Dziadosz M, Goworek J (2011) Synthesis and characterization of nanostructural polymer-silica composite: Positron annihilation lifetime spectroscopy study. J Colloid Interface Sci 358;1:268–276
  • 28. Zaleski R, Stefaniak W, Maciejewska M, Goworek J (2010) Porosity evolution of VP-DVB/MCM-41 nanocomposite. J Colloid Interface Sci 343;1:134–140
  • 29. Zaleski R, Wawryszczuk J (2008) Positron porosimetry studies of template removal from as-synthesized MCM-41 silica. Acta Phys Pol A 113;5:1543–1550
  • 30. Zaleski R, Wawryszczuk J, Goworek J, Borówka A, Goworek T (2003) Vacuum removal of the template in MCM-41 silica studied by the positron annihilation method. J Colloid Interface Sci 262;2:466–473
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ8-0025-0081
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