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Proceedings of the 9th All - Polish Seminar on Mössbauer Spectroscopy OSSM'2012, 10-13 June 2012, Lublin - Kazimierz Dolny, Poland
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Abstrakty
X-ray diffraction measurements and Mossbauer spectroscopy with external magnetic field were carried out on (Cr0.99 57Fe0.01)3+xSi-x alloys. The Mossbauer spectra for A15 type of structure can be described by superposition of single line S(1) and two doublets D(1) and D(2). The relative ratio of the S(1) and D(2) strongly depends on x. The nearest neighbours of these components have been identified. It was shown that 57Fe atoms preferentially locate in Cr positions for x less-than or equal to 0.0, while for x greater 0.0 iron atoms are distributed both in Cr and Si positions. It was shown that, in A15 structure, one Cr atom located in the 57Fe nearest neighbours (n.n.) decreases isomer shift by (0.022 plus or minus 0.002) mm/s, while one Si in n.n. increases isomer shift by (0.09 plus or minus 0.01) mm/s. The measured Mossbauer spectra of bcc Cr-Si indicate that atoms are randomly distributed and can be well described as superposition of single lines, related to various local environments of 57Fe atoms.
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Tom
Strony
73--76
Opis fizyczny
Bibliogr. 16 poz., rys.
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autor
autor
autor
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- University of Bialystok, Faculty of Physics, 41 Lipowa Str., 15-424 Białystok, Poland, Tel.: +48 85 745 7242, Fax:+48 85 745 7223, satula@alpha.uwb.edu.pl
Bibliografia
- 1. Akai H, Blügel S, Zeller R, Dederichs PH (1986) Isomer shifts and their relation to charge transfer in dilute Fe alloys. Phys Rev Lett 56:2407–2410
- 2. Bei H, George EP, Kenik EA, Pharr GM (2003) Directional solidification and microstructures of near-eutectic Cr-Cr3Si alloys. Acta Mater 51:6241–6252
- 3. Bei H, George EP, Pharr GM (2003) Effects of composition on lamellar microstructure of near-eutectic Cr-Cr3Si alloys. Intermetallics 11:283–289
- 4. Blaes N, Fisher H, Gonser U (1985) Analytical expression for the Mössbauer line shape of 57Fe in the presence of mixed hyperfine interactions. Nucl Instrum Methods B 9:201–208
- 5. Blaugher RD, Hein RE, Cox JE, Waterstrat RM (1969) Atomic order and superconductivity in A15 compounds. J Low Temp Phys 1;6:539–561
- 6. Carol H, Gauben H, Templeton DH, Myers CE (1956) The crystal structure of Cr5Si3. J Phys Chem 60;4:443–445
- 7. Curse TA, Newkirk JW (1997) Evaluation of methods to produce tough Cr3Si based compounds. Mater Sci Eng A 239/240:410–418
- 8. Dubiel SM, Żukrowski J (1981) Mössbauer effect study of charge and spin transfer in Fe-Cr. J Magn Magn Mater 23:214–228
- 9. Ingalls R, Drickamer HG, De Pasquali G (1967) Isomer shift of Fe57 in transition metals under pressure. Phys Rev 155:165–170
- 10. Massalski TB (1990) Binary alloy phase diagrams. American Society for Metals, Metals Park, OH, pp 1333–1335
- 11. Radovskii IZ, Shubina TS, Gel’d PV, Sidorenko FA (1965) The magnetic susceptibility of chromium silicides. Powder Metall Met C+ 4:115–121
- 12. Satuła D, Szymański K, Dobrzyński L, Waliszewski J (1993) Mössbauer study of Fe3-xCrxSi alloys with DO3-type ordering. J Magn Magn Mater 119:309–317
- 13. Stearns MB (1963) Internal magnetic fields, isomer shifts, and relative abundances of the various Fe sites in FeSi alloys. Phys Rev 129:1136–1144
- 14. Wijn HPJ (eds) (1991) Magnetic properties of metals, d-elements, alloys and compounds. Springer, Berlin
- 15. Zaleski P, Szymański K, Olszewski W et al. (2011) Local structure and magnetism of Fe, Co and Ni doped Cr3Si. Physica B 406:3196–3205
- 16. Zaleski P, Szymański K, Przewoźnik J, Rećko K, Cottrell S, Dobrzyński L (2010) Cr3Si doped by Co studied by muon spin relaxation and scanning electron microscopy techniques. J Alloys Compd 498:5–12
Typ dokumentu
Bibliografia
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bwmeta1.element.baztech-article-BUJ8-0025-0049