Mössbauer spectroscopy study of 60P2O5-40Fe2O3 glass

• Autorzy: Stoch P. , Ciecińska M. , Zachariasz P. , Suwalski J. , Górski L. , Wójcik T.
• Konferencja: Proceedings of the 9th All - Polish Seminar on Mössbauer Spectroscopy OSSM'2012, 10-13 June 2012, Lublin - Kazimierz Dolny, Poland
• Języki publikacji: EN

Abstrakty

EN

A 57Fe Mössbauer spectroscopy study is presented. The main goal of the research was to investigate the structural information of the glass-like the coordination numbers and redox ratio of the iron. Most of the iron, about 80%, is present in the glass as Fe3+, which is composed of tetrahedral (57%) and octahedral (23%) coordinated iron. The rest of the iron, about 20%, is in the oxidation state Fe2+. This iron could be mostly present as VIFe2+, but five-fold coordinated iron is also possible. Finally, the structural model of the synthesized 60P2O5-40Fe2O3 glass was proposed.

Słowa kluczowe

EN

iron phosphate glass; Mössbauer spectroscopy; nuclear waste; waste glass

• Wydawca: Institute of Nuclear Chemistry and Technology
• Czasopismo: Nukleonika
• Rocznik: 2013
• Tom: Vol. 58, No. 1
• Strony: 63--66
• Opis fizyczny: Bibliogr. 10 poz., rys.

Twórcy

autor

Stoch P.

autor

Ciecińska M.

autor

Zachariasz P.

autor

Suwalski J.

autor

Górski L.

autor

Wójcik T.

• AGH University of Science and Technology, Faculty of Materials Science and Ceramics, al. A. Mickiewicza 30, 30-059 Krakow, Poland and National Centre for Nuclear Research, 7 Andrzeja Sołtana Str., 05-400 Otwock/Świerk, Poland, Tel.: [phone],,

Bibliografia

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