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Tytuł artykułu

EPR study on sugar radicals utilized for detection of radiation treatment of food

Treść / Zawartość
Identyfikatory
Warianty tytułu
Konferencja
Proceedings of the International Conference on Development and Applications of Nuclear Technologies NUTECH-2011, 11-14 September 2011, Kraków, Poland
Języki publikacji
EN
Abstrakty
EN
Radicals produced by ionizing radiation in sugars, the components of dried and raw fruits give rise to stable multicomponent electron paramagnetic resonance (EPR) signals unidentified so far. The subject of the present EPR study is to identify the radicals stabilized in gamma-irradiated crystalline sugars, D(+)mannose and L(-)sorbose extracted from cranberries (Vaccininum oxycoccos) and rowan berries (Sorbus aucuparia), respectively. EPR measurements and density functional theory (DFT) simulations were employed for that purpose.
Czasopismo
Rocznik
Strony
545--549
Opis fizyczny
BIbliogr. 13 poz., rys.
Twórcy
autor
autor
  • Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: +48 22 504 1205, Fax: +48 22 811 1532, j.michalik@ichtj.waw.pl
Bibliografia
  • 1. Collins PM (ed) (2005) Dictionary of carbohydrates. CRC Press, Hoboken
  • 2. Da Costa ZM, Pontuschka WM, Campos LL (2005) A comparative study based on dosimetric properties of different sugars. Appl Radiat Isot 62:331–336
  • 3. European Committee for Standardisation (2001) EN-13708:2001E: Foodstuffs-detection of irradiated food containing crystalline sugar by ESR spectroscopy. CEN, Brussels
  • 4. Glaser D (2002) Specialization and phyletic trends of sweetness reception in animals. Pure Appl Chem 74;7:1153–1158
  • 5. Guzik GP, Stachowicz W, Michalik J (2008) Study on stable radicals produced by ionizing radiation in dried fruits and related sugars by electron paramagnetic resonance spectrometry and photostimulated luminescence method – I. D-fructose. Nukleonika 53;Suppl 2:S89–S94
  • 6. Karakirova Y, Yordanov ND, De Cooman H, Vrielinck H, Callens F (2010) Dosimetric characteristics of different types of saccharides: An EPR and UV spectrometric study. Radiat Phys Chem 79:654–659
  • 7. Merck Index (1999) 12th Edition, 8874
  • 8. Nakajima T, Otsuki T (1990) Dosimetry for radiation emergencies: radiation-induced free radicals in sugar of various countries and the effect of pulverizing on the ESR signal. Appl Radiat Isot 41:359–365
  • 9. Raffi J, Angel J-P (1989) Electron spin resonance identification of irradiated fruits. Radiat Phys Chem 34;6:891–894
  • 10. Raffi J, Stachowicz W, Migdał W et al. (1998) Establishment of an eastern network of laboratories for identification of irradiated foodstuffs. Final Report of Copernicus Concerted Action, CIPA-CT94-0134, CCE
  • 11. Stachowicz W, Strzelczak G, Michalik J, Wojtowicz A, Dziedzic-Gocławska A, Ostrowski K (1992) Application of EPR spectroscopy for control of irradiated food. J Sci Food Agric 58:407–415
  • 12. Vanhaelewyn G, Jansen B, Pauwels E, Sagstuen E, Waroquier M, Callens F (2004) Experimental and theoretic al electron magnetic resonance study on radiation-induced radicals in L-sorbose single crystals. J Phys Chem A 108:3308–3314
  • 13. Vanhaelewyn G, Lahorte P, Proft F, Mondelaers W, Geerlings P, Callens F (2001) Electron magnetic resonance study of stable radicals in irradiated D-fructose single crystals. J Phys Chem Chem Phys 3;9:1709–1735
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ8-0023-0046
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