Mercury(II) Ions Transport from Aqueous Solutions Using Liquid Membrane Systems

Alpoguz, H. K.; Kaya, A.; Sener, I.

Artykuł - szczegóły

Tytuł artykułu

Mercury(II) Ions Transport from Aqueous Solutions Using Liquid Membrane Systems

Autorzy

Alpoguz H. K. , Kaya A. , Sener I.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

The transport behavior of Hg2+ from donor aqueous solution into a receiving aqueous solution through bulk and supported liquid membranes containing a calix[4]arene derivative 1 as a car rier was in ves ti gated. The kinetic parameters of bulk liquid membrane were analyzed as suming two consecutive, irreversible first-order reactions. The influence of temperature, stirring rate, carrier concentration and solvent on the kinetic parameters (k1, k2, Rm max , tmax, Jd max , Ja max ) has also been investigated. The activation energy values are calculated as 13.4 and 1.41 kcal mol–1 for extraction and reextraction, respectively. The activation energy values indicate that the process is diffusionally controlled by species. In addition, the transport behavior of Hg2+ from aqueous solution through a flat-sheet supported liquid membrane has been investigated by the use of calix[4]arene derivative 1 as carrier and Celgard 2500 as the solid support. A Danesi mass transfer model was used to calculate the permeability coefficients for each parameter (type of solvent and anion).

Słowa kluczowe

liquid membrane calixarenes transport kinetics transport of mercury(II)

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2009

Tom

Vol. 83, nr 11

Strony

2021--2033

Opis fizyczny

Bibliogr. 42 poz., rys.

Twórcy

autor

Alpoguz H. K.

autor

Kaya A.

autor

Sener I.

Department of Chemi try, Pamukkale University, 20070 Kinikli-Denizli, Turkey Tel: +90-258-2963600; Fax: +90-258-2963535, hkalpoguz@pau.edu.tr

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Typ dokumentu

Bibliografia

Identyfikator YADDA

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