Direct Transformation of Ethanol to Ethyl Acetate over MoSx/C Catalyst

• Autorzy: Wang L. X. , Zheng D. F. , Ma C. X. , Zhu W. C. , Liu S. Y. , Cui J. , Wang Z. L. , Zhang W. X.
• Języki publikacji: EN

Abstrakty

EN

Activated carbon-supported sulfided molybdenum catalysts were tested in transformation of ethanol to ethyl acetate. The catalytic activity of MoSx/C catalysts was found to depend strongly on preparation procedure. Surface atomic ratio of S/Mo on these catalysts was different and the catalyst with the ratio of S/Mo = 2.2 had better catalytic properties. For the purpose of enhancement of catalytic activity, the treatment of activated carbon support by HNO3 had been applied. Physicochemical characterization showed that the pretreatment was effective in obtaining a highly dispersed molybdenum species on the surface of the catalyst, which led to an in crease in conversion of ethanol.

Słowa kluczowe

EN

ethyl acetate; ethanol; activated carbon MoSx/C catalyst

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2009
• Tom: Vol. 83, nr 11
• Strony: 1993--2000
• Opis fizyczny: Bibliogr. 21 poz., rys.

Twórcy

autor

Wang L. X.

autor

Zheng D. F.

autor

Ma C. X.

autor

Zhu W. C.

autor

Liu S. Y.

autor

Cui J.

autor

Wang Z. L.

autor

Zhang W. X.

• College of Chemistry, Jilin University, Changchun 130021, P. R. China Tel.: [phone]

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