Selective Synthesis of Z-1,4-Disilyl-2-butenes

• Autorzy: Šabata S. , Blechta V. , Karban J. , Pleska A. , Včelák J. , Hetflejš J.
• Języki publikacji: EN

Abstrakty

EN

Z-1,4-Disilyl-2-butenes, R3SiCH2CH=CHCH2SiR3 (R3 = Me3, Me2H, Me2(ClCH2), Me2Ph(CH2)3, Me(2-Bu)2 and Et3) have been prepared in high yields by the reaction of 1,4-dilithio-2-butene with the corresponding trialkylchlorosilanes, using tert-butyl methyl ether as the solvent. The course of an analogous reaction of dimethyldichlorosilane is briefly discussed.

Słowa kluczowe

EN

Z-1,4-disilyl-2-butenes; 1,4-dilithio-2-butene; trialkylchlorosilanes; stereo controlled synthesis; alkadiene disilylation

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2009
• Tom: Vol. 83, nr 11
• Strony: 1953--1958
• Opis fizyczny: Bibliogr. 26 poz., rys.

Twórcy

autor

Šabata S.

autor

Blechta V.

autor

Karban J.

autor

Pleska A.

autor

Včelák J.

autor

Hetflejš J.

• Institute of Chemical Process Fundamentals, Academy of Sciences of the Czech Republic, Rozvojova 135, 145 02 Prague 6-Suchdol, Czech Republic,,

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