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Two Supramolecular Complexes with Hydrogen-bonds of N-H ··· O and C-H ··· O between Dicarboxylic Acids and Bis-imidazoles

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Two imidazole derived supra molecular complexes (N,N'-butylenebis(imidazole) : (tere - phthalic acid)2 (1), and N,N'-butylenebis(imidazole) : sebacic acid (2)) were synthesized and structurally characterized by X-ray crystallography. Compounds 1 and 2 both crystallize in the triclinic P-1 space group. In compound 1, one-dimensional grid structure is formed through imidazolium moieties hydrogen bonded to mono-ion carboxylate groups of two par al lel terephthalate chains. Ad ja cent grids packed along the b axis through C-H ··· O hydrogen bonds form 3D network. For compound 2, with strong O-H ···N hydrogen bonds, the bis(imidazole) and the sebacic acid are arranged alternatively to form 1D in finite chain, which is further stacked into a 3D net work structure through additional C-H ··· O hydrogen bonds.
Słowa kluczowe
Rocznik
Strony
1937--1944
Opis fizyczny
Bibliogr. 35 poz., rys.
Twórcy
autor
autor
autor
autor
  • Department of Chemistry, Faculty of Science, ZheJiang Forestry University, Lin’An Hangzhou 311300, P. R. China Tel & fax: +86-571-6374-0010, jinsw@zjfc.edu.cn
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ7-0016-0002
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