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Abstrakty
A series of Mo-V-O catalysts for the selective oxidation of isobutane were prepared by a hydrothermal method and by a solution reaction. The synthesis method, catalyst composition and calcination temperature have great effect on the catalytic behavior. Catalytic tests showed that MoV0.3 catalyst prepared by a hydrothermal method exhibited the best catalytic behavior. Using this catalyst 10.7 per cent selectivity to methacrolein and 15.3 per cent selectivity to methacrylic acid can be achieved at an isobutane conversion of 10.4 per cent at 380 graduate C.
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Czasopismo
Rocznik
Tom
Strony
1831--1836
Opis fizyczny
Bibliogr. 13 poz., rys.
Twórcy
autor
autor
autor
autor
autor
autor
autor
- College of Chemistry, Jilin University, Jiefang Road 2519, Changchun, 130023, P.R. China Tel./fax: +86-431-88499140, qkan@mail.jlu.edu.cn
Bibliografia
- 1. Mizuno N, Tateishi M. and Iwamoto M., J. Catal, 163, 87 (1996).
- 2. Guan J., Wu S., Wang H., Jing S., Wang G., Zhen K. and Kan Q., J. Catal, 251, 354 (2007).
- 3. GrasselliR.K.,BhandariR., SwaminathanB., Vasudevan V.K., BrongersmaH.H., Knoester A., Gaffney A.M. and Han S., J. Phys. Chem. B, 109,24046 (2005).
- 4. Baca M., Aouine M., Dubois J.L. and Millet J.M.M., J. Catal, 233, 234 (2005).
- 5. Murayama H., Vitry D., Ueda W, Fuchs G, Anne M. and Dubois LL.,Appl. Catal. A, 318,137 (2007).
- 6. Oshihara K., Hisano T. and Ueda W, Top. Catal, 15, 153 (2001).
- 7. Tsuji H. and Koyasu Y., J. Am. Chem. Soc., 124, 5608 (2002).
- 8. Aouine M, Millet J.M.M. and Dubois J.L., Chem. Commun., 13, 1180(2001).
- 9. Guan J., Xu H., Song K., Liu B., Shang F., Yu X. and Kan Q., Catal. Lett., 126, 293 (2008).
- 10. Guan J.Q., Wu S.J., Shao Y.Q., Ma YY, Shang RR, Yu X.F., Liu J. and Kan Q.B., Polish J. Chem., 83, 605 (2009).
- 11. Guliants V.V., Bhandari R., Swaminathan B., Vasudevan V.K., Brongersma H.H., Knoester A. and Gaffhey A.M., J. Phys. Chem. B, 109, 24046 (2005).
- 12. Grasselli R.K., Burrington J.D., Buttrey D.J., DeSanto Jr. P., Lugmair CG., Volpe Jr. A.F. and Weingand T., Top. Catal, 23, 5(2003).
- 13. Ueda W, Vitry D. and Katou T., Catal. Today, 96, 235 (2004).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ7-0015-0092