Hydrothermal Synthesis and Structures of Two Isostructural Mixed Complexes of Cd and Mn with 2,3-Dicarboxylatopyrazine and Phenanthroline

• Autorzy: Zhang M. -S. , Sun B. -W. , Fang R. -B. , Zhao Q. -H.
• Języki publikacji: EN

Abstrakty

EN

Two polyaromatic acid transition metal complexes: {[Cd(phen)(O2C)2C4N2H2]źH2O}n (1), and {[Mn(phen)(O2C)2C4N2H2]źH2O}n (2) (phen = 1,10-phenanthroline) have been hydrothermally synthesized and characterized by elemental analyses, IR spectroscopy, and single-crystal X-ray diffraction. The structural analysis reveals that compound 1 and compound 2 are almost isostructural. The metal atoms are linked by bridging 2,3-di -carboxylatopyrazine ligands to form 2-D layer network, and have a coordination number six.

Słowa kluczowe

EN

polyaromatic acid; hydrothermal synthesis; transition metal complexes

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2009
• Tom: Vol. 83, nr 10
• Strony: 1701--1706
• Opis fizyczny: Bibliogr. 15 poz., rys.

Twórcy

autor

Zhang M. -S.

autor

Sun B. -W.

autor

Fang R. -B.

autor

Zhao Q. -H.

• School of Chemical Science and Engineering, Key Laboratory of Natural Resources and Medicinal Chemistry, Yunnan University, Kunming 650091, P. R. China,

Bibliografia

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