Synthesis, Characterization and Reactivity of Bis(4-tert-butylphenolato)dichlorotin(IV)

• Autorzy: Chaudhry S. C. , Bandna K. , Bhatt S. S. , Sharma N.
• Języki publikacji: EN

Abstrakty

EN

The bis(4-tert-butylphenolato)dichlorotin(IV) complex of composition SnCl2(OC6H4But-4)2 (1) has been synthesized by the reaction of tin tetrachloride with bimolar amount of 4-t-butylphenol in benzene under reflux and characterized by elemental analyses, molar conductance measurements, molecular weight determination, IR, 1H, 13C NMR and FAB mass spectral techniques. Thermal behaviour of the complex has been investigated using TG-DTA technique. Lewis acid character of (1) has been explored by isolating its addition compounds with some nitrogeneous bases viz. diethylamine, triethylamine, imidazole, benzimidazole (L); 2,2'-bipyridyl, and 1,10-phenanthroline (B) of composition, SnCl2(OC6H4But-4)2×2L and SnCl2(OC6H4But-4)2×B, characterized by physicochemical and IR spectral studies.

Słowa kluczowe

EN

tin(IV) compound; 4-t-butylphenol; thermal studies; spectral properties; acceptor properties

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2009
• Tom: Vol. 83, nr 9
• Strony: 1537--1545
• Opis fizyczny: Bibliogr. 29 poz., rys.

Twórcy

autor

Chaudhry S. C.

autor

Bandna K.

autor

Bhatt S. S.

autor

Sharma N.

• Department of Chemistry, Himachal Pradesh University, Summer Hill, Shimla – 171005, India,

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