Regioselective Cleavage of 2-Aryloxymethyloxiranes to 3-Aryloxy-1-halogenopropan-2-ols

• Autorzy: Maciejewski M. , Półtorak K. , Kamińska J. E.
• Języki publikacji: EN

Abstrakty

EN

A series of new 2-aryloxymethyloxiranes prepared from epichlorohydrin and substituted phenols was subjected to nucleophilic opening of the oxiranering. A comparison of regioselectivity and product yield for oxirane cleavage by means of aqueous hydrohalogenic acids or lithium tetrahalogenocuprates under an hydrous conditions was performed. The latter method provided very high regioselectivity for 3-aryloxy-1-halogeno propan-2-ols as well as excellent yields.

Słowa kluczowe

EN

2-aryloxymethyloxirane; regioselective oxirane cleavage; 3-aryloxy-1-halogenopropan-2-o; 3-aryloxy-2-halogenopropan-1-ol; lithium tetrahalogenocuprate

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2009
• Tom: Vol. 83, nr 4
• Strony: 595--604
• Opis fizyczny: Bibliogr. 21 poz., rys.

Twórcy

autor

Maciejewski M.

autor

Półtorak K.

autor

Kamińska J. E.

• Institute of General Food Chemistry, Łódź University of Technology, ul. Stefanowskiego 4/10, 90-924 Łódź, Poland,

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