Synthesis and Characterization of Some Borylated (4-Biphenyl)(N-arylamino)glyoxime Complexes

• Autorzy: Karipcin F. , Erdem-Tuncmen M.
• Języki publikacji: EN

Abstrakty

EN

A series of Cu(II), Ni(II) and Co(III) complexes of the type [M(Ln)2(H2O)2(BF2)2] and [Co(Ln)2PyCl(BF2)2] (where M = Cu(II) or Ni(II); n = 1, 2; L = bidentate dioxime lig ands) have been synthesized by the reactions of dioxime complexes with boron tri- fluoride diethyl ether complex in acetonitrile under nitrogen atmosphere. In all these reactions, the bridging protons of the dioxime com plexes replace BF2 groups. These complexes have been characterized by elemental analyses, FT-IR, ICP-OES, 1H NMR together with magnetic susceptibility measurements. In particular, the thermal decomposition of all the complexes was studied in nitrogen atmosphere.

Słowa kluczowe

EN

dioxime; borylated; biphenyl; thermal decomposition

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2009
• Tom: Vol. 83, nr 4
• Strony: 525--535
• Opis fizyczny: Bibliogr. 24 poz., rys.

Twórcy

autor

Karipcin F.

autor

Erdem-Tuncmen M.

• Süleyman Demirel University, Department of Chemistry, 32260, Isparta, Turkey Fax: [phone]

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