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Synthesis of Ho(Fe1–xCox)2 intermetallic compounds, studies of their crystal structure and 57Fe Mössbauer effect analysis were carried out at 295 K. X-ray measurements evidence a pure cubic Fd3m, C15, MgCu2-type Laves phase. The unit cell parameter decreases non-linearly with composition parameter x. Mössbauer effect spectra for the Ho(Fe1–xCox)2 series were composed of a number of locally originated subspectra due to random Fe/Co nearest neighbourhoods. Hyperfine interaction parameters, i.e. isomer shift, the magnetic hyperfine field and a quadrupole interaction parameter were determined from the fitting procedure of the spectra, for both the individual nearest neighbourhoods, and for the sample as bulk. As a consequence of Fe/Co substitution a Slater-Pauling type curve for the average magnetic hyperfine field vs. x is observed. The correlation between the local magnetic hyperfine fields and the average magnetic hyperfine fields is related to weak and strong ferromagnetism of the transition metal sublattice.
Czasopismo
Rocznik
Tom
Strony
279--284
Opis fizyczny
Bibliogr. 29 poz., rys.
Twórcy
autor
autor
autor
autor
autor
autor
- Faculty of Physics and Applied Computer Science, AGH University of Science and Technology, 30 A. Mickiewicza Ave., 30-059 Kraków, Poland, Tel.: +48 12 617 2990, Fax: +48 12 634 0010, pszczola@agh.edu.pl
Bibliografia
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- 19. Stoch P, Pszczoła J, Guzdek P, Chmist J, Pańta A (2005)Electrical resistivity studies of Dy(Fe1–xCox)2 compounds. J Alloys Compd 394:116–121
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ7-0014-0044