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Differentiation between fossil and biofuels by liquid scintillation beta spectrometry - direct method

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Języki publikacji
EN
Abstrakty
EN
Liquid scintillation spectrometry of 14C in gasoline/ethanol and diesel oil was carried out using QuantulusŽ and straight mixtures of fuel and an organic scintillation cocktail. A linear correlation was found between the concentration of carbon that originates from the bioethanol (biocarbon) and the fuel mixture’s 14C activity in the range 0–100% (m/m) bioethanol content. Because of these good linear correlations, quantitative determination of a fuel’s biocarbon content can be made by 14C analysis. The direct method is also applicable to analysis of the bio-based materials dissolvable in solvents, which can be mixed with scintillation cocktails.
Słowa kluczowe
Czasopismo
Rocznik
Strony
127--131
Opis fizyczny
Bibliogr. 16 poz., rys.
Twórcy
autor
autor
  • PerkinElmer LAS (Germany) GmbH, Ferdinand-Porsche-Ring 17, 63110 Rodgau, Germany, Tel.: +49 0 172 638 5909, Fax: +49 0 421 620 8425, Ronald.Edler@perkinelmer.com
Bibliografia
  • 1. American Society for Testing and Materials (ASTM) (2006) Vol. 8.03. Method D6866-06. Standard test methods for determining the biobased content of natural range materials using radiocarbon and isotope ratio mass spectrometry analysis. www.astm.org
  • 2. Aravena R, Drimmie RR, Qureshi RM, McNeely R, Fabris S (1989) New possibilities for 14C measurements by liquid scintillation counting. Radiocarbon 31:387–392
  • 3. Baxter MS, Walton A (1971) Carbon-14 concentrations in recent wines and spirits. J Food Sci 36:540–541
  • 4. Dijs IJ, van der Windt E, Kaihola L, van der Borg K (2006) Quantitative determination by 14C analysis of the biological component in fuels. Radiocarbon 48;3:315–323
  • 5. Directive 2003/30/EC of the European Parliament and of the Council of 8 May 2003 on the promotion of the use of biofuels or other renewable fuels for transport. Official Journal of the European Union (17.05.2003)
  • 6. Edler R (2006) Cocktails for liquid scintillation counting. LSC Application Note 16. PerkinElmer LAS, Germany
  • 7. Edler R (2009) The use of liquid scintillation counting technology for the determination of biogenic materials. In: LSC 2008: Advances in Liquid Scintillation Spectrometry. Proceedings of the 2008 Int Liquid Scintillation Conf, 25–30 May 2008, Davos, Switzerland
  • 8. Gupta SK, Polach HA (1985) Radiocarbon dating practices at ANU. Handbook. Radiocarbon Laboratory, Research School of Pacific Studies, Australian National University, Canberra
  • 9. Higham T, Radiocarbon (web-info). http://www.c14dating. com
  • 10. McWeeny DJ, Bates ML (1980) Discrimination between synthetic and natural ethyl alcohol in spirits and fortified wines. J Food Technol 15:407–412
  • 11. Martin GE, Noakes JE, Alfonso FC, Figert DM (1981) Liquid scintillation counting of Carbon-14 for differentiation of synthetic ethanol from ethanol of fermentation. Journal of the Association of Official Analytical Chemists 64:1142–1144
  • 12. Noakes JE, Norton G, Culp R, Nigam M, Dvoracek D (2007) A comparison of analytical methods for the certification of biobased products. LSC2005, advances in liquid scintillation spectrometry. Radiocarbon 49:259–272
  • 13. Qureshi RM, Aravena R, Fritz P, Drimmie RR (1989) The CO2 absorption method as an alternative to benzene synthesis method for C14 dating. Appl Geochem 4:625–633
  • 14. Schönhofer F (1989) Determination of 14C in alcoholic beverages. Radiocarbon 31;3:777–784
  • 15. Thomson J, Burns DA (2005) Radio-carbon (14CO2) trapping and counting. Application note CS-001. PerkinElmer LAS, Germany (updated May 2005 by R. Edler)
  • 16. US Department of Agriculture, Federal Biobased Products Preferred Procurement Program (FB4P), 7 CFR 2902, Designation of biobased items for federal procurement. http://www.biobased.oce.usda.gov/files/03-31347.pdf
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ7-0014-0022
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