PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Ortho-positronium in liquid alkanes

Autorzy
Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Positron lifetime spectra were measured for a series of odd-numbered liquid n-alkanes (C7H16, C9H20, C13H28 and C19H40) in a broad range of temperature. According to the “bubble model” the ortho-positronium (o-Ps) lifetime is determined by surface tension. Bubble radius was calculated using the Tao-Eldrup model and compared to the radius expected from the surface tension of liquid. The radii are not identical, their difference rises with temperature. If one assumes the difference of radii as constant, the o-Ps lifetime calculated from the Tao-Eldrup model rises faster than the experimental one. The distinct rise of the difference of radii has no physical explanation in the accepted o-Ps annihilation model. This effect can be the result of radiation chemistry processes not taken into account so far in the bubble model.
Czasopismo
Rocznik
Strony
41--46
Opis fizyczny
Bibliogr. 30 poz., rys.
Twórcy
  • Institute of Physics, Maria Curie-Skłodowska University, 1 M. Curie-Skłodowskiej Sq., 20-031 Lublin, Poland, Tel.: +48 81 537 6261, Fax: +48 81 537 6191, bozena@hektor.umcs.lublin.pl
Bibliografia
  • 1. Ahn WS, Jhon M, Pak H, Chang S (1972) Surface tension of curved surfaces. J Colloid Interf Sci 38:605–608
  • 2. Brandt W, Berko S, Walker WW (1960) Positronium decay in molecular substances. Phys Rev 120:1289–1295
  • 3. Buchikhin AP, Goldanskii VI, Shantarovich VP (1971) Temperaturnaya zavisimost’ vremieni zhizni tripletnogo pozitroniya v alifaticheskikh uglevodorodakh i ikh proizvodnykh. Pisma v ZETF 13:624–627
  • 4. Buchikhin AP, Goldanskii VI, Tatur AO, Shantarovich VP (1971) Atom pozitroniya v organicheskikh zhidkostyach. ZETF 60:1136–1140
  • 5. Byakov VM, Krištiak J (1996) On the relationship between o-Ps lifetime in liquids and their surface tension. J Radioanal Nucl Chem 211:11–14
  • 6. Byakov VM, Stepanov SV (2000) Microscopic surface tension of liquids with curved free boundary studied by positron annihilation. Radiat Phys Chem 58:687–692
  • 7. Duplatre G, Billard I (2003) Organic and inorganic chemistry of the positron and positronium. In: Jean YC, Mallon PE, Schrader DM (eds) Principles and applications of positron and positronium chemistry. World Scientific, Singapore, pp 73–116
  • 8. Duplatre G, Haessler A, Abbe JCh (1985) Interaction of Ps with Co2+ in water: mechanism and temperature effects. J Phys Chem 89:1756–1760
  • 9. Eldrup M, Lightbody D, Sherwood JN (1981) The temperature dependence of positron lifetimes in solid pivalic acid. Chem Phys 63:51–58
  • 10. Ferrel RA (1957) Long lifetime of positronium in liquid helium. Phys Rev 108:167–168
  • 11. Garwin RL (1953) Thermalization of positrons in metals. Phys Rev 91:1571–1572
  • 12. Gey RB, Chai KJ (1992) Ps-bubble states in organic liquids determined from o-Ps lifetime distributions. Mater Sci Forum 105/110:1573–1576
  • 13. Goworek T (2002) Not only pick-off. In: Proc of the 34th Polish Seminar on Positron Annihilation, 16–21 June 2002, Turawa, Poland, pp 157–178 (in Polish)
  • 14. Jasińska B, Kozioł AE, Goworek T (1999) Void shapes and o-Ps lifetime in molecular crystals. Acta Phys Pol A 95:557–561
  • 15. Jasper JJ (1972) The surface tension of pure liquid compounds. J Phys Chem Ref Data 1;4:841–1009
  • 16. Jasper JJ, Kring EV (1955) The isobaric surface tension and thermodynamic properties of the surfaces of a series of n-alkanes, C5 to C18, 1-alkenes, C6 to C16, and of n-decylcyclopentane, n-decylcyclohexane and n-decylbenzene. J Phys Chem 59:1019–1021
  • 17. Kajcsos Zs, Dezsi I, Horvath D (1974) Positron lifetime measurements in aliphatic hydrocarbons. Appl Phys 5:53–56
  • 18. Kansy J (1996) Microcomputer program for analysis of positron annihilation lifetime spectra. Nucl Instrum Methods Phys Res A 373:235–244
  • 19. Melrose J (1966) Model calculations for capillary condensation.Am Inst Chem Eng 12:986–694
  • 20. Mogensen OE, Jacobsen FM (1982) Positronium yieldsin liquids determined by lifetime and angular correlation measurements. Chem Phys 73:223–234
  • 21. Nakanishi H, Wang SJ, Jean YC (1987) Microscopic surface tension studied by positron annihilation. In: Sharma SC (ed) Positron annihilation studies of fluids. World Scientific, Singapore, pp 292–298
  • 22. Northby JA, Sanders TM (1967) Photoejection of electrons from bubble states in liquid helium. Phys Rev Lett 18:1184–1186
  • 23. Roellig LO (1967) Positron annihilation. In: Stewart AT, Roellig LO (eds) Positron annihilation. Academic Press, New York, p 127
  • 24. Schmelzer J, Mahnke R (1986) General formulae for the curvature dependence of droplets and bubbles. J Chem Soc Faraday Trans 1;82:1413–1420
  • 25. Schrader DM, Jean YC (eds) (1988) Positron and positronium chemistry. Elsevier, Amsterdam. Vol. 57, p 166
  • 26. Stepanov S, Byakov VM, Duplatre G, Zvezhinskiy DS, Lomachuk YV (2009) Positronium formation in a liquid phase: influence of intratrack reactions and temperature. Phys Status Solidi C 6:2476–2481
  • 27. Stepanov SV, Byakov VM, Ganguly BN, Gangopadhyay D, Mukherjee T, Dutta-Roy B (2002) A molecular basis of the bubble model of positronium annihilation in liquids. Phys B 322:68–79
  • 28. Tao SJ (1972) Positronium annihilation in molecular substances. J Chem Phys 56:5499–5510
  • 29. Ujihira Y, Ryuo T, Kobayashi Y, Nomizu T (1978) Dependence of ortho-positronium pick-off annihilation lifetime on free volume in organic molecular liquids calculated by Kincaid Eyring method, and positronium bubble formation. Appl Phys 16:71–74
  • 30. Vavruch I (1995) On the evaluation of the surface tension – pressure coefficient of pure liquids. J Colloid Interface Sci 169:249–250
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ7-0014-0009
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.