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Stable isotope composition of carbon dioxide emitted from anthropogenic sources in the Kraków region, Southern Poland

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Języki publikacji
EN
Abstrakty
EN
The summary of the measurements of CO2 stable isotopic composition emitted from different anthropogenic sources in the Krakow region is presented. The sources are divided into three main groups . high emission (electric and heat power plants), low emission (coal and methane burning in the households) and car traffic (gasoline, diesel and LPG supplied engines equipped and not equipped with catalyst). Presented results include two measurement campaigns made in the years 1995 and 2000. The measurements revealed three well-defined groups with respect to carbon isotope composition (delta13CVPDB): .30.60 plus-minus sign 0.37 per mille (thousand) sign (car traffic) .23.82 plus-minus sign 0.10 per mille (thousand) sign (coal burning) and .51.8 plus-minus sign 1.1per mille (thousand) sign (methane burning). The oxygen isotope composition (delta18OVPDB-CO2) of CO2 varied in a broad range, from ca. .11per mille (thousand) sign to ca. .22 per mille (thousand) sign, the most negative values being observed for coal and methane burning and the most positive for cars equipped with a catalyst. No significant isotopic shift has been observed between two measurement campaigns.
Czasopismo
Rocznik
Strony
291--295
Opis fizyczny
Bibliogr. 11 poz., rys.
Twórcy
autor
Bibliografia
  • 1. Allison CE, Francey RJ, Meijer HAJ (1995) Recommendations for the reporting of stable isotope measurements of carbon and oxygen in CO2 gas. In: Reference and intercomparison materials for stable isotopes of light elements. IAEA, Vienna. IAEA-TECDOC-825, pp 155–162
  • 2. Clark-Thorne ST, Yapp CJ (2003) Stable carbon isotope constraints on mixing and mass balance of CO2 in an urban atmosphere: Dallas metropolitan area, Texas, USA. Appl Geochem 18:75–95
  • 3. Grimmond CSB, King TS, Cropley FD, Nowak D, Souch C (2002) Local-scale fluxes of carbon dioxide in urban environments: methodological challenges and results from Chicago. Environ Pollut 116:S243–S254
  • 4. Kotarba M (1988) Geochemical criteria for the origin of natural gases accumulated in the upper carboniferous coal-seam-bearing formations in Walbrzych coal basin. Zeszyty Naukowe no. 1199, AGH University of Science and Technology, Kraków (in Polish)
  • 5. Kroopnick P, Craig H (1972) Atmospheric oxygen: isotopic composition and solubility fractionation. Science 175:54–55
  • 6. Kuc T, Rozanski K, Zimnoch M, Necki J, Chmura L, Jelen D (2007) Two decades of regular observations of 14CO2 and 13CO2 content in atmospheric carbon dioxide in central Europe: long-term changes of regional anthropogenic fossil CO2 emissions. Radiocarbon 49;2:358–375
  • 7. Levin I, Kromer B, Schmidt M, Sartorius H (2003) A novel approach for independent budgeting of fossil fuels CO2 over Europe by 14CO2 observations. Geophys Res Lett 30:2194–2198
  • 8. Mirosław J (1997) Isotopic composition of methane in atmosphere over Kraków. PhD Thesis. AGH University of Science and Technology, Kraków (in Polish)
  • 9. Mlicki M (2000) Isotope identification of anthropogenic sources of carbon dioxide in Kraków. Master Thesis. AGH University of Science and Technology, Kraków (in Polish)
  • 10. Zimnoch M, Florkowski T, Necki JM, Neubert REM (2004) Diurnal variability of δ13C and δ18O of atmospheric CO2 in the urban atmosphere of Kraków, Poland. Isot Environ Health Stud 40;2:129–143
  • 11. Zondervan A, Maijer HAJ (1996) Isotopic characterization of CO2 sources during regional pollution events using isotopic and radiocarbon analysis. Tellus 48B:601–612
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ7-0008-0037
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