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Proceedings of the International Conference on Recent Developments and Applications of Nuclear Technologies 15-17 September 2008, Białowieża, Poland
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Detergents at waters inducing negative changes for biological degradability and water general quality. Some authors have evidenced a considerable amount of anionic surfactant and toxic effects into natural water and effluents related to detergents. The objective of the study was to apply electron irradiation for reducing toxicity, and for degradation of surfactants. To quantify surfactant LAS determination as MBAS (metylene blue active substances) was applied. The capacity of radiation to reduce surfactants was evidenced for real effluent and for water solution containing sodium dodecyl sulfate, linear alkylbenzene sulfonate (LAS), separately. An electron beam accelerator (EBA) 1.5 MeV was the radiation source. Anionic surfactant solutions as well as real effluents resulted in less toxic samples after irradiation. Toxicity was evaluated for Vibrio fischeri and Daphnia similis. An important decline of total anionic surfactant was observed after irradiation to doses: 6.0 kGy and 20 kGy (surfactant in water solutions and effluents, respectively). To conclude, EBA irradiations accounted for 88% to 96% less toxic surfactants solutions and effluents and 68% to 96% for MBAS compounds decomposition.
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Tom
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61--64
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Bibliogr. 13 poz., rys.
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- Radiation Technology Center (IPEN-CNEN/SP), 2242 Prof. Lineu Prestes Ave., 05508-000, Săo Paulo, Brazil, Tel.: +55 11 3133 9817, Fax: +55 11 3133 9765, sborrely@ipen.br
Bibliografia
- 1. ABNT NBR 12713 (2004) Aquatic ecotoxicology-acute toxicity – assay method for Daphnia spp (Cladocera crustacea)
- 2. ABNT NBR 15411-2 (2006) Aquatic ecotoxicology –determination of light emision inibitory effect for Vibrio fischeri into water samples (part 2)
- 3. APHA/AWWA/WPCF (1995) Standard methods for the examination of water and wastewater, 19th ed. American Public Health Association, New York
- 4. Bigardi TAR, Nunes AJT, Carra LP, Fadini PS (2003)Destination of anionic surfactants at WWTP – aerated lagoons and decantation. Environmental and Sanitary Engeneering 8:45–48
- 5. Borrely SI, Sampa MHO, Uemi M, Del Mastro NL, Silveira CG (1998) Domestic effluent: disinfection and organic matter removal by ionizing radiation. In: Cooper WJ, Curry R, O’Shea K (eds) Environmental applications of ionizing radiation. Wiley, New York, pp 369–380
- 6. CETESB (1987) Surfactants survey at aquatic environment. Ambiente 1 Journal
- 7. Chemistry and derivation. www.quimicaederivados.com.br/revista/qd438/detergentes4.html
- 8. Getoff N (1996) Radiation-induced degradation of water pollutants – state of the art. Radiat Phys Chem 47:581–593
- 9. Kurucz CN, Waite TD, Cooper WJ, Nieckelsen MG (1991) High energy electron beam irradiation of water, wastewater and sludge. Adv Nucl Sci Technol 23:1–13
- 10. Moraes MCF, Romanelli MF, Sena HC, Pasqualini da Silva G, Sampa MHO, Borrely SI (2004) Whole acute toxicity removal from industrial and domestic effluents treated by electron beam radiation: emphasis on anionic surfactants. Radiat Phys Chem 71:463–465
- 11. Podzorova EA, Pikaev AK, Belyshev VA, Lysenko SL 1988) New data on electron-beam treatment of minicipal wastewater in the aerosol flow. Radiat Phys Chem 52:361–364
- 12. Rohrer DM (1975) Effects of gamma radiation from 60Co on dilute aqueous of linear alkyl sulfonate surfactants and other organic pollutants. In: Proc of the Symp Radiation for a Clean Environment, Munich, Germany, pp 241–248
- 13. Romanelli MF, Moraes MCF, Villavicencio ALCH, Borrely SI (2004) Evaluation of toxicity reduction of sodium dodecyl sulfate submitted to electron beam radiation.Radiat Phys Chem 71:411–413
Typ dokumentu
Bibliografia
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bwmeta1.element.baztech-article-BUJ7-0008-0001