Synthesis, Characterization and Catalytic Activity of Resin-based Diiron(III) Interphase Catalysts: Model for Methane Monooxygenase

• Autorzy: Shan C. , Qian G. R. , Zhang L. , Luo Y. L.
• Języki publikacji: EN

Abstrakty

EN

Three resin-based m-oxo diiron(III) interface catalysts have been successfully prepared to model the functional properties of methane monooxygenase (MMO). The catalysts were characterized and exhibited the catalytic activities in the oxidation of alkanes to responding alcohols and ketones in acetonitrile at room temperature by 30% hydroperoxide (H2O2) or tert-butyl hydroperoxide (TBHP) as the oxidants. For 2,6-di-tert-butylphenol as the substrate, the C-C coupling was found in the two reaction systems. The reaction mechanisms were proposed with the predominant radical mechanism.

Słowa kluczowe

EN

methane monooxygenase; interface catalyst; resin; catalytic activity

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2009
• Tom: Vol. 83, nr 1
• Strony: 163--168
• Opis fizyczny: Bibliogr. 26 poz., rys.

Twórcy

autor

Shan C.

autor

Qian G. R.

autor

Zhang L.

autor

Luo Y. L.

• Department of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China phone and Fax: [phone],

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