Regioselective Reaction of 2-Hydroxyliminoimidazolidine-O-sulfonate with Benzyl Bromides

• Autorzy: Sączewski J. , Gdaniec M.
• Języki publikacji: EN

Abstrakty

EN

Triethylaminium 2-hydroxylaminoimidazolidine-O-sulfonate was alkylated at the exocyclic N2 nitrogen atom of the 2-iminoimidazolidine moiety to give 2-benzyl-2- hydro-xylamino-4,5-dihydroimidazolium-O-sulfonates. The structure of products was confirmed by X-ray crystallographic analysis. The obtained compounds upon treatment with carbon disulfide were further converted into bis(2-benzyl amino- 4,5-dihydroimidazol-1-yl)methanethiones.

Słowa kluczowe

EN

2-iminoimidazolidines; N-benzylation reaction; quantum chemical calculation; X-ray crystallographic analysis

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2008
• Tom: Vol. 82, nr 11
• Strony: 2107--2113
• Opis fizyczny: Bibliogr. 16 poz., rys.

Twórcy

autor

Sączewski J.

autor

Gdaniec M.

• Department of Chemical Technology of Drugs, Medical University of Gdańsk, Al. Gen. J. Hallera 107, 80-416 Gdansk, Poland,

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