Substituent Effect on Aniline Carbonylation Reaction in the Presence of the PdCl2/Fe/I2/Py Catalytic System

• Autorzy: Karpińska M. , Baran P. , Skupińska J.
• Języki publikacji: EN

Abstrakty

EN

A study of the effect of substituents in the aromatic ring on the aniline carbonylation reaction in the presence of the PdCl2/Fe/I2/Py catalytic system, where oxygen or nitrobenzene were used as oxidants, showed that the electronodonor substituents accelerate the aniline carbonylation reaction, when the reaction is conducted in the presence of oxygen. For nitrobenzene used as an oxidant in this reaction substituent was found to have no ef fect on the carbamate yield. The nitrobenzene reduction is the rate-determining step in the aniline carbonylation process.

Słowa kluczowe

EN

substituted aniline; carbonylation; palladium chloride; substituent effect

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2008
• Tom: Vol. 82, nr 5
• Strony: 1105--1116
• Opis fizyczny: Bibliogr. 43 poz., rys.

Twórcy

autor

Karpińska M.

autor

Baran P.

autor

Skupińska J.

• Laboratory of Physicochemical Fundaments of Chemical Technology, Department of Chemistry, The University of Warsaw, 02-093 Warsaw, Pasteura 1, Poland fax: [phone],

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