A Mixed Ligand Copper(II) Complex with 5,5-Dimethylhydantoin and t-Butylamine

• Autorzy: Tas M. , Soylu M. S. , Büyükgüngör O.
• Języki publikacji: EN

Abstrakty

EN

The structure of the newly synthesized complex, trans- bis(t- butyl amine)- bis(5,5- di - methylhydantoinato)copper(II) dihydrate was determined by single crystal X-ray crystallography. Thermal analyses, FT-IR spectra and magnetic susceptibility were also studied. The complex crystallizes in the orthorhombic system, space group Pbca. The complex has a slightly distorted square planar [CuN4] coordination with 5,5-dimethyl - hydantoinato and t-butylamine ligands bonded to the copper(II) ion via their de protonated N(3) and amine nitrogen atoms, respectively. The Cu-N hyd. and Cu-N amine bond lengths are 1.983 and 2.019 A.

Słowa kluczowe

EN

hydantoins; 5,5-dimethylhydantoin; t-butylamine; copper(II) complex

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2008
• Tom: Vol. 82, nr 5
• Strony: 973--980
• Opis fizyczny: Bibliogr. 22 poz., rys.

Twórcy

autor

Tas M.

autor

Soylu M. S.

autor

Büyükgüngör O.

• Giresun University, Faculty of Arts and Sciences, Department of Chemistry, 28049 Giresun, Turkey,

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