Influence of Rotational - Vibrational Coupling on Shape of Rovibrational Bands

• Autorzy: Dudziec P. , Konarski J.
• Języki publikacji: EN

Abstrakty

EN

The integrated absorption coefficient of rovibrational bands is calculated for three different cases, namely for separated rotational and vibrational motions, for the non-rigid model which takes into account the coupling between above mentioned motions using the Kratzer-Fues potential and the soft body model, for which only rovibrational states exist. It is shown that the shape of P and R bands for higher rotational quantum numbers depends on the applied model of rotational - vibrational transitions.

Słowa kluczowe

EN

intensity; IR-transitions; quantum dynamics

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2008
• Tom: Vol. 82, nr 4
• Strony: 751--757
• Opis fizyczny: Bibliogr. 19 poz., rys.

Twórcy

autor

Dudziec P.

autor

Konarski J.

• Faculty of Chemistry, A. Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland,

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