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New materials and ideas to be used in adiabatic engines

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EN
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EN
This note concerns several topics. Firstly, a review of some less-known topics regarding the contemporary knowledge on TBC and piston caps is given. Then, it turns out that almost unknown New Periodic System of Elements can be of assistance to predict several properties of new TBC materials. Theoretically, there exist a possibility to join Si-AL-piston alloy with yttria-stabilised zirconia (and the like) by means of feId spars (plagioclase). The latter do not attain to melting temperature and can be arrested within the alloy. A shortened integral optical equation in the manner of inverse problem was used to compute the temperature drop accros the piston cap's layers. The YSZ layer operating in this hypothetical engine gave 517.5 graduate K drop, whereas the feldspar gave about 100-50graduate K temperature drop per mm. This arrangement would give minimised radiation and more or less 'cold' engine(piston). Perhaps, oxides of the thalium-sesquioxide-type structure would be better to stick to metal than the commonly used ones.
Twórcy
  • Cracow University of Technology Institiite of Vehicles and IC Engines, 31-155 Cracow, Warszawska 24, Poland Phone: (12)62825 89
autor
  • Cracow University of Technology Institiite of Vehicles and IC Engines, 31-155 Cracow, Warszawska 24, Poland Phone: (12)62825 89
Bibliografia
  • [1] Bast, U. And Schumann, E., Development of novel oxide materials for TBC’s, Cer. Eng. & Sci. Proc., 2002, p.525-532.
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  • [4] Chigrinova, N. M., Primenenie oksidnoy keramiki v kachestve funktsionalnykh zashchitnykh bar’erov, Ogneup. i tekh. Ker., 2001/11, p.4-8.
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  • [6] Eldridge, J.l., Spuckler, C. M. and Street, K. W., Infrared radiative properties of yttria-stabilized zirconia thermal barrier coatings; ibidem, p. 417-430.
  • [ 7] Filatov. S. K., Vvedenie v vysokotemperaturnuyu kristallokhimiyu, in: Kristallokhimiya i strukturnyy tipomorfizm mineralov, Frank-Kameneckiy, V. A [Ed.], Nauka, Moskva, 1985. p.21-56.
  • [8] Herve Ph., Le relations de Fresnel dans l’infrarouge. Verification et applications a la determination de l’emissivite et de l’indice complexe. Rev.int.haul. Temp. Refract., 1979. p.263-275.
  • [9] lvanova. L. P., Romashin, A.G., Burovova. N. D. and Kryuchkov, V.A., Poluchenie i svoystva tsirkonevoy keramiki, Ogneup., 1991/2. p. 6-9.
  • [10] Jaskólski J., Zagadnienia optymalizacji obciążeń cieplnych tłoków silników spalinowych, Wyd. P. Cz., Częstochowa, 2001, 101 pp.
  • [ 11] Klethkovskaya, V. V., Khitrova, V. L., Sagitov, S. I. and Semiletov, S. A. Issledovanie vliyaniya otzhiga na strukturnye i opticheskie svoystva plenok dvuokisi tsirkoniya, Kristall., 1980. p. 1107-1109.
  • [12] Krzyżak, R., The mineralogical aspects of (radiative) conductivity of ceramics. in: Fundamental'nye i prikladnye problemy sovershenstvovaniya porshnevykh dvigateley IX. Mezhdunarodnaya nauchno-prakticheskaya konferentsiya - materialy., Vladimir, 2003. p. 69-72.
  • [13] Karaulov, A G. and Zoz, E. I., Issledovanie tverdykh rastvorov sistemy Zr02-HfO2-SiO2 i poluchenie novykh ogneupornykh materialov na ikh osnove, Ogneup.1991/2, p.11- 13.
  • [14] Lingart, Yu. K. and Shtipel’man, Ya. I., Issledovaniya temperaturnykh poley v ustanovkakh dlya vyrashchivaniya monokristallov leykosapfira s pomoshchyu matematicheskogo modelirovaniya, lnzh.-Fiz. Zh., 1982/2. p. 306-314.
  • [15] Magnitskiy, V. A., Petrunin. G. I. and Yurchak, R. P., Povedenie temperaturoprovodnosti nekotorykh polevykh shpatov i plagioklazov pri temperaturakh 300-1200oK, Dokl. Akad. nauk SSSR, 1971/199, p. 1058-1060.
  • [16] Marakushev, A. A. , K teorii geokhimicheskikh processov, in: Geokhemicheskie metody pri poiskakh skrytogo orudneniya, Nazarov, A. V. [Ed.], Nauka, Leningrad, 1984. p.77-101.
  • [ 17] McCullough, J. D. and Trueblood, K. N., The crystal structure of baddelyite (Monoclinic ZrO2), Acta Crysl., 1959, 507-511.
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  • [21] Mirkovich, V. V., Thermal diffusivity of Ba-mica/ yttria-stabilized zirconia composites. Rev. lnt. haut Temp. Refract., 1979, 346-349.
  • [22] Schelling, P. K., Phillpot, S. R. and Grimes, R. W., Optimum pyrochlore compositions for low thermal conductivity, Phil. Mag. Lett., 2004, p. 127-137.
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  • [24] Skagggs, S. R., Zero and low coefficient of thermal expansion polycrystallinc oxides.; ibidem. p. 157-167.
  • [25] Smetannikova. O. G., Kamentsev. l. E. and Vande-Kirkov, Yu. V., Osobennosti Al.-Si uporyadochennosti v ryadu plagioklazov razlichnogo sostava, in: Kristallokhimiya i rentgenografia mineralog, Frank-Kamenetskiy, V. A. [Ed.], Nauka, Leningrad. 1987. p. 63-74.
  • [26] Willaime, C., Brown, W. L. and Perucaud, M. C., On the orientation of the thermal and compositional strain ellipsoids in feldspars, Am. Mineral., 1974, 457-464.
  • [27] Woods, M. E., Mandler, W. F. Jr. and Scofield, T. L., Designing ceramic insulated components for the adiabatic engine, Cer. Bull., 1985, p. 287-293.
  • [28] Wu, J. et al. , Low-thermal-conductivity rare-earth zirconates for potential thermal-barrier-coating applications, J. Am. Ceram. Soc., 2002, p. 3031-3035.
  • [29] Zhu, D. and Miller, R. A., Thermal conductivity and sintering behavior of advanced thermal barrier coatings, Cer. Eng. & Sci. Proc., 2002, p. 457-468.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ6-0024-0024
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