Solid Sodium Hydrox ide - THF, Convenient System for Synthesis Esters of Glycidic Acids by Darzens Condensation

• Autorzy: Gadaj A. , Kowalkowska A. , Jończyk A.
• Języki publikacji: EN

Abstrakty

EN

Isopropyl- and tert-butylchloroacetate react with carbonyl compounds in the presence of powdered sodium hydroxide in THF, with out a catalyst, giving substituted glycidates. The process is applied for preparation of glycidates from ketones, hitherto unavailable by phase-transfer catalyzed Darzens condensation.

Słowa kluczowe

EN

Darzens condensation; chloroacetates; sodium hydroxide; glycidic esters

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2008
• Tom: Vol. 82, nr 3
• Strony: 577--584
• Opis fizyczny: Bibliogr. 32 poz., rys.

Twórcy

autor

Gadaj A.

autor

Kowalkowska A.

autor

Jończyk A.

• Warsaw University of Technology, Faculty of Chemistry, Koszykowa St. 75, 00-662 Warsaw, Poland,

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