Synthesis and Solid State Characterization of Organometallic Polymer of Ag(I) Using 2,2-Dimethyl-1,3-diisocyano Propane Ligand

• Autorzy: Al-Ktaifani M. M. , Rukiah M. K. , Shaaban A. K.
• Języki publikacji: EN

Abstrakty

EN

2,2-Dimethyl-1,3-diisocyano propane CNCH2C(CH3)2CH2NC was prepared and fully characterized by IR and multi-nuclear NMR spectroscopy. Treatment of CNCH2C(CH3)2CH2NC with AgCl afforded al most quantitatively highly in soluble powder. Its X-ray powder diffractional studies revealed a polymeric structure. In this structure the Ag centres are bridged with each of the two adjacent Ag neighbours by the bidentate ligands CNCH2(CH3)2CH2NC via the NC groups to form {Ag(CNCH2(CH3)2CH2NC)}n chains. The Cl- counter part an ions are cross linked the Ag centres of the chains to form a polymeric network {[Ag(CNCH2(CH3)2CH2NC)]Cl}n.

Słowa kluczowe

EN

diisocyanide; Ag complex; powder X-ray structure; bidentate; polymeric structure; Rietveld refinements

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2008
• Tom: Vol. 82, nr 3
• Strony: 547--557
• Opis fizyczny: Bibliogr. 22 poz., rys.

Twórcy

autor

Al-Ktaifani M. M.

autor

Rukiah M. K.

autor

Shaaban A. K.

• Atomic Energy Commission of Syria (AECS), Damascus - P. O. Box 6091, Syrian Arab Republic Fax: [phone],

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