Different Complexation Behavior of a Proton Transfer Compound Obtained from Pyridine-2,6-dicarboxylic Acid and Creatinine with Tl(I), Cu(II), Fe(III) and Bi(III): Synthesis, Characterization, Crystal Structures and Solution Studies

• Autorzy: Aghabozorg H. , Ramezanipour F. , Soleimannejad J. , Sharif M. A. , Shokrollahi A. , Shamsipur M. , Moghimi A. , Attar Gharamaleki J. , Lippolis V. , Blake A. J.
• Języki publikacji: EN

Abstrakty

EN

The different complexation methods of a proton transfer compound, (creatH)(pydcH)źH2O (pydcH2 = pyridine-2,6-di carboxylic acid; creat = creatinine) with metal ions have been studied and formation of [(Tl(pydcH)]n (1), [(Fe(pydc)(H2O)2)2ox]ź6H2O (2), [Cu(pydc)(pydcH2)]ź2H2O (3) and (creatH)2[Bi(pydc)2]2ź4H2O (4) are re ported. The characterization was performed using IR spectroscopy and single crystal X-ray diffraction analysis. The Tl(I) complex [(Tl(pydcH)]n (1) obtained from (creatH)(pydcH)źH2O is a polymeric system, showing only the contribution of the anionic species of (creatH)(pydcH)źH2O to the complexation. The Fe(III) and the Cu(II) complexes [(Fe(pydc)(H2O)2)2ox]ź6H2O (2) (ox = ox a late) and [Cu(pydc)(pydcH2)]ź2H2O (3) were also obtained from (creatH)(pydcH)źH2O. The Bi(III) complex (creatH)2[Bi(pydc)2]2ź4H2O (4) is a dimeric system, showing both contribution of the cationic and anionic fragments. The complexes 1-4 show a variety of structural features including mononuclear, binuclear, polymeric structures and unusual ligand formation. In compounds (1), (2), (3) and (4), a large number of hydrogen bonds are observed. These interactions as well as p-p stacking play an important role in the formation and stabilization of supra molecular systems in the crystal lattices. The stoichiometry and stability of the Cu(II), Tl(I) and Bi(III) complexes with (pydc)(creat) and Fe(III) with pydc-ox mixture in aqueous solution were investigated by potentiometric pH titration.

Słowa kluczowe

EN

thallium; iron; copper; bismuth; proton transfer compound; creatinine; pyridine-2,6-di carboxylic acid; X-ray crystal structure; hydrogen bonds; solution studies

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2008
• Tom: Vol. 82, nr 3
• Strony: 487--507
• Opis fizyczny: Bibliogr. 37 poz., rys.

Twórcy

autor

Aghabozorg H.

autor

Ramezanipour F.

autor

Soleimannejad J.

autor

Sharif M. A.

autor

Shokrollahi A.

autor

Shamsipur M.

autor

Moghimi A.

autor

Attar Gharamaleki J.

autor

Lippolis V.

autor

Blake A. J.

• 1De part ment of Chem is try, Teacher Training University, 49 Mofateh Avenue, 15614, Teheran, Iran Tel.: [phone]; Fax: [phone],

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