Synthesis, Characterization and Catalytic Activity of the Manganese(III) - Schiff Base Complexes

• Autorzy: Szypa M. , Pelech R.
• Języki publikacji: EN

Abstrakty

EN

Symmetrical and un symmetrical mangaese(III) Schiff base complexes of the type [MnClLLc], (LLc = [ONNO] = symmetrical and unsymmetrical Schiff base derivatives of trans-1,2-diaminocyclohexane and 2-hydroxynaphthaldehyde as well as R-salicyl - aldehydes) were synthesized by the reactions of the appropriate Schiff base with Mn(CH3COO)3ź4H2O and lithium chloride. The complexes were characterized by elemental analysis, IR and UV-vis spectrometric methods. The catalytic activity of the prepared complexes was studied in the epoxidation of styrene and cyclohexene.

Słowa kluczowe

EN

Schiff base; manganese(III) complexes; epoxidation; alkanes

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2008
• Tom: Vol. 82, nr 3
• Strony: 481--486
• Opis fizyczny: Bibliogr. 27 poz., rys.

Twórcy

autor

Szypa M.

autor

Pelech R.

• 1Institute of Chemistry and Environmental Protection, Szczecin University of Technology, Al. Piastów 42, 70-065 Szczecin, Poland tel.[phone], fax. [phone]

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