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Effect of gamma-irradiation on aqueous solutions of Apollofix dyes

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Radiation processing has been considered as a promising process for the treatment of textile industry waste effluents. In this study, the possibility of using gamma-rays to degrade and decolorize Apollofix dyes in water has been investigated. Two different Apollofix dyes, Apollofix Red (AR) and Apollofix Yellow (AY) in aqueous solutions were irradiated in air with doses from 1.0 kGy to 8.0 kGy at a 0.14 kGy/h of dose rate. The change in absorption spectra, pH, chemical oxygen demand (COD), biological oxygen demand (BOD) and the degree of decoloration (percent reduction in optical density) were examined in the presence and absence of H2O2. The absorption bands at 534 nm and 420 nm for AR and AY were observed to decrease rapidly with increasing irradiation dose. The degree of decoloration of each dye solution with irradiation dose was estimated as 100 percent for the lower concentration (50 ppm) dye solutions. The complete decoloration was observed after 2.0 kGy and 1.0 kGy doses for AR and AY dyes. The COD and BOD reduction and the change of pH for all dye solutions on irradiation showed similar behavior.
Czasopismo
Rocznik
Strony
109--113
Opis fizyczny
Bibliogr. 20 poz., rys.
Twórcy
autor
autor
autor
  • Department of Chemistry, Hacettepe University, 06532, Beytepe-Ankara, Turkey, Tel.: +90 312 2977990, Fax: +90 312 2992163, solpan@hacettepe.edu.tr
Bibliografia
  • 1. Allen AO (1961) The radiation chemistry of water and aqueous solutions. Van Nostrand Co., Princeton, New Jersey
  • 2. American Public Health Association (1971) Standard methods for the examination of water and wastewater,13th ed. American Public Health Association, Washington, DC
  • 3. Clarke EA, Anliker R, Hutzinger O (1980) The handbook of environmental chemistry. Vol. 3A. Springer, Berlin
  • 4. Craft TF, Eichholz GG (1971) Synergistic treatment of textile dye wastes by irradiation and oxidation. Int J Appl Radiat Isot 22:543−547
  • 5. Hosono M, Arai H, Aizawa M, Yamamoto I, Shimizu K, Sugiyama M (1993) Decoloration and degradation of azo dye in aqueous solution supersaturated with oxygen by irradiation of high-energy electron beam. Appl Radiat Isot 44;9:1199−1203
  • 6. Morris RD, Craft TF (1973) Degradation of acid dyes by irradiation plus oxidation. Int J Appl Radiat Isot 24:245−252
  • 7. Nagai T, Suzuki N (1976) The radiation-induced degradation of anthraquinone dyes in aqueous solutions.Int J Appl Radiat Isot 27:699−705
  • 8. Poulis I, Tsachpinis I (1999) Photodegradation of the textile dye reactive black 5 in the presence of semiconducting oxides. J Chem Technol Biotechnol 74:349−357
  • 9. Shevchuck IA, Makhno A, Ditrikh IV (1993) Rapid determination of chemical oxygen demand in glucose water solutions. Khim Technol Vody 15:262−263
  • 10. Solpan D, Güven O (2002) Decoloration and degradation of some textile dyes by gamma irradiation. Radiat Phys Chem 65:549−558
  • 11. Solpan D, Güven O, Takács E, Wojnárovits L, Dajka K (2003) High-energy irradiation treatment of aqueous solutions of azo dyes: steady-state gamma radiolysis experiments. Radiat Phys Chem 67:531−534
  • 12. Spinks JWT, Woods RJ (1964) An introduction to radiation chemistry. Chapter 8. Wiley, New York
  • 13. Suzuki N, Nagai T, Hotta H, Washino HM (1975) The radiation-induced decoloration of azo dye in aqueous solutions. Bull Chem Soc Jpn 48;7:2158−2163
  • 14. Suzuki N, Nagai T, Hotta H, Washino HM (1975) The radiation-induced degradation of azo dyes in aqueous solution. Int J Appl Radiat Isot 26:726−730
  • 15. Suzuki N, Nagai T, Hotta H, Washino HM (1976) The radiolysis of anthraquinone dye in aqueous solutions. Bull Chem Soc Jpn 49;3:600−605
  • 16. Tanaka K, Padermpole K, Hisanaga T (2000) Photocatalytic degradation of commercial azo dyes. Water Res 34;1:327−333
  • 17. Uygur A (1997) An overview of oxidative and photooxidative decolorisation treatments of textile wastewaters. J Soc Dyers Colour 113:211−217
  • 18. Vinodgopal K, Kamat PV (1998) Hydroxyl-radicalmediated oxidation: a common pathway in the photocatalyticdegradation of textile dyes. In: Cooper WJ, Curry RD, O’Shea KE (eds) Environmental applications of ionizing radiation. Wiley, New York, pp 587−599
  • 19. Wojnárovits L, Pálfi T, Takács E, Emmi SS (2005)Reactivity differences of hydroxyl radicals and hydrated electrons in destructing azo dyes. Radiat Phys Chem 74:239−246
  • 20. Zhang S, Yu H, Zhao Y (2005) Kinetic modeling of the radiolytic degradation of acid orange 7 in aqueous solutions. Water Res 39:839−846
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ6-0023-0053
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