Synthesis, Structure and Third-Order Nonlinear Optical Properties of a Iodoargentate(I) Cluster Polymer of [(Et4N)(Ag2I3)]n

• Autorzy: Zhang X. , Li Y. , Li K. , Song W. , Wang C. , Pan L.
• Języki publikacji: EN

Abstrakty

EN

Apolynuclear silver(I) cluster polymer [(Et4N)(Ag2I3)]n 1 with iodo-bridging ligands has been prepared by low-temperature solid-state reaction. Single crystal X-ray analyses reveal that compound 1 possesses a new type of one-dimensional (1-D) structure. The cluster anion of the title compound can be described as polymeric chain with [Ag2I2] plane. This cluster polymer shows nice third-order nonlinear optical (NLO) absorption and refraction with absorption coefficient alfa 2 = 9.1×10-11 mźw-1 and refractive index n2 = -3.4×10-17 m2źw-1 in a 2.6×10-4 molźdm-3 DMF solution.

Słowa kluczowe

EN

iodoargentate(I) cluster; structure; nonlinear optical properties

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2007
• Tom: Vol. 81, nr 7
• Strony: 1313--1320
• Opis fizyczny: Bibliogr. 27 poz., rys.s.

Twórcy

autor

Zhang X.

autor

Li Y.

autor

Li K.

autor

Song W.

autor

Wang C.

autor

Pan L.

• College of Science, Guangdong Ocean University, Zhanjiang 524088, Guangdong Province, P. R. China

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