Structural and Spectroscopic Study of trans-Bis(1,3,5-trimethylpyrazole)-bis(O,O'-nitrate) Copper(II) Complex

• Autorzy: Wiśniewski Z. , Wojciechowska A. , Kochel A. , Wysokiński R.
• Języki publikacji: EN

Abstrakty

EN

Cu II complex with 1,3,5-trimethylpyrazole (1,3,5-TMePz) trans-[Cu(1,3,5-TMePz)2(NO3)2] has been prepared and studied by X-ray diffraction, vibrational and electronic spectroscopy. The complex crystallizes in the orthorhombic crystal system, P212121 space group with lattice parameters:a = 7.6784(8),b = 13.5856(11), c = 16.3372(13) capital A ring, V = 1704.2(3)capital A ring 3 and Z = 4. The hydrogen bond system stabilizes the crystal structure. Two nitrogen atoms of 1,3,5-TMePz and four oxygen atoms of chelating NO-3 groups form a trans-CuIIN2O2O2 ' chromophore.

Słowa kluczowe

EN

Cu(II) complex; methyl pyrazoles; nitrate ion; spectroscopic study; X-ray structure

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2007
• Tom: Vol. 81, nr 7
• Strony: 1277--1288
• Opis fizyczny: Bibliogr. 26 poz., rys..

Twórcy

autor

Wiśniewski Z.

autor

Wojciechowska A.

autor

Kochel A.

autor

Wysokiński R.

• Institute of Chemistry, Świętokrzyska Academy, ul. Chęcińska 5, 25-020 Kielce, Poland

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