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Abstrakty
The distribution of promoters in the reduced form of iron catalyst for the ammonia synthesis was studied using the selective etching method and the electron microscopy technique with EDX analyzer. During the reduction process, calcium and aluminium incorporated into amagnetite particle, do not migrate but they form the CaOźAl2O3 phase. It was found that approximately 30% of the total amount of aluminium is separated in the Al2O3 form.
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Strony
433--440
Opis fizyczny
Bibliogr. 9 poz., rys.
Twórcy
autor
- Szczecin University of Technology, Institute of Chemical and Environment Engineering, 70-322 Szczecin, Pulaskiego 10, Poland
Bibliografia
- 1. Schlogl R., Preparation and activation of the technical ammonia synthesis catalyst. In: J.R. Jennings,editor. Catalytic Ammonia Synthesis: Fundamental and Practice. Plenum Press, New York, 1991, pp.16-108.
- 2. Stoltze R, Structure and surface chemistry of industrial ammonia synthesis catalysts. In: K. Aika, et al.,Ammonia Catalysis and Manufacture. Springer-Verlag, Berlin, 1995, p. 21-88.
- 3. Silverman D.C. and Boudart M., J. Catal, 77, 208 (1982).
- 4. Dry M.E. and Ferreira L.C., J. Catal., 7, 352 (1967).
- 5. Lendzion-Bieluń Z. and Arabczyk W., Applied Catal. A: General, 207, 37 (2001).
- 6. Lendzion-Bieluń Z., Arabczyk W. and Figurski M., Applied Catal A: General, 227, 255 (2002).
- 7. Figurski M., Arabczyk W., Lendzion-Bieluń Z., Kaleńczuk R.J. and Lenart S., Applied Catal. A:General, 247, 9 (2003).
- 8. Arabczyk W., Ziebro J, Kałucki K., Świerkowski R. and Jakrzewska M., Chemik, l, 22 (1996).
- 9. Pernicone N. and Traina F., Preparation of Catalysts, Stud. Surf. Sci. Catal, 3, 321 (1979).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ6-0011-0030