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Mixed-ligand trinuclear Cu(II) complex involving trithiocyanurate(3-) anion (ttc3-) and N,N,N',N' , N'-pentamethyldiethylenetriamine (pmdien) in the coordination sphere of composition [Cu3(pmdien)3(mi-ttc)](ClO4)3 has been prepared. The complex has been characterized by EA, IR, UV-Vis, and mass spectroscopy. We can assume, that the complex is trinuclear with central atoms connected by trithiocyanurate(3-) bridges. Each central atom is in deformed trigonal bypiramidal arrangement formed by chelating S,N atoms of ttc(3-) and by three N atoms of pmdien. Temperature dependence of magnetic susceptibility and EPR spectroscopy have also been employed to characterize the compound. Magnetic susceptibility measurements over the 1.8-300 K temperature range revealed antiferromagnetic interactions among central atoms. The antitumor activity in vitro against G-361 (human malignant melanoma), HOS (human osteogenic sarcoma), K-562 (human chronic myelogenous leukaemia) and MCF-7 (human breast adenocarcinoma) tumor cell lines have been tested but unfortunately the complexes showed no cytotoxic activity against the four cell lines.
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Tom
Strony
327--335
Opis fizyczny
Bibliogr. 40 poz., rys.
Twórcy
autor
autor
autor
autor
autor
autor
- Department of Inorganic Chemistry, Palacký University, Kříkovského 10, CZ-771 47 Olomouc, Czech Republic
Bibliografia
- 1. Gatteschi D., Kahn 0. and Willet R.D., Magneto-Structural Correlations in Exchange Coupled Systems,Reidel, Dordrecht, 1984.
- 2. Kahn 0., Molecular Magnetism, VCH Publishers, New York, 1993.
- 3. Mrozinski J., Coord. Chem. Rev., 249, 2534 (2005).
- 4. Ferrer S., Haasnoot J.G., Reedijk J., Muller E., Cingi M.B., Lanfranchi M., Lanfredi A.M.M. and Ribas J., Inorg. Chem., 39, 1859 (2000).
- 5. Ferrer S., Lloret F., Bertomeu I., Alzuet G., Borras J., Garcia-Granda S., Liu-Gonzalez M. and Haasnoot J.G., Inorg. Chem., 41, 5821 (2002).
- 6. Mirica L.M. and Stack T.D.P., Inorg. Chem., 44, 2131 (2005).
- 7. Kopel R, Travniček Z., Marek J., Korabik M. and Mroziński J., Polyhedron, 22, 411 (2003).
- 8. Kopel R, Travniček Z., Marek J. and Mroziński J., Polyhedron, 23, 1573 (2004).
- 9. Kopel R, Šindelaf Z. and Klička R., Transition Met. Chem., 23, 139 (1998).
- 10. Kopel R, Travniček Z., Kvitek L., Panchartkova R., Biler M., Marek J. and Nadvornik M., Polyhedron, 18, 1779(1999).
- 11. Kopel R, Travniček Z., Kvitek L., Čemošek Z., Wrzeszcz G. and Marek J., J. Coord. Chem., 56, l (2003).
- 12. Kopel R, Travniček Z., PanchartkovaR., BilerM. andMarek J., Transition M et. Chem., 24,239 (1999).
- 13. Kopel R, Travniček Z., Panchartkova R., Šindelaf Z. and Marek J., J. Coord. Chem., 44, 205 (1998).
- 14. Kopel R, Travniček Z., Kvitek L., Biler M., Pavlićek M., Šindelaf Z. and Marek J., Transition Met. Chem., 26,282(2001).
- 15. Marek J., Kopel R and Travniček Z., Acta Cryst., C59, m558 (2003).
- 16. Yamanari K., Kushi Y., Yamamoto M., Fuyuhiro A., Kaizaki S., Kawamoto T. and Kushi Y., J. Chem. Soc. Dalton. Trans., 3715 (1993).
- 17. Hunks W.J., Jennings M.C. and Puddephatt R.J., Inorg. Chem., 38, 5930 (1999).
- 18. Cecconi F., Ghilardi C.A., Midollini S. and Orlandini A., J. Organomet. Chem., 645, 101 (2002).
- 19. Haiduc L, Mahoń M.F., Molloy K.C. and Venter M.M., J. Organomet. Chem., 627, 6 (2001).
- 20. Kar S., Miller T.A., Chakraborty S., Sarkar B., Pradhan B., Sinha R.K., Kundu T., Ward M.D. and Lahiri G.K., Dalton Trans., 2591 (2003).
- 21. Kar S., Pradhan B., Sinha R.K., Kundu T., Kodgire R, Rao K.K., Puranik V.D. and Lahiri G.K., Dalton Trans., 1752(2004).
- 22. König E., Magnetic Properties of Coordination and Organometallic Transition Metal Compounds, Springer, Berlin, 1966, p. 1.
- 23. Travniček Z., Malon M., Šindelaf Z., Doležal K., Rolcik J., Krystofy, Strnad M. and Marek J., J. Inorg. Biochem.,84, 23(2001).
- 24. Travniček Z., Malon M., Zatloukal M., Doležal K., Stmad M. and Marek J., J. Inorg. Biochem., 94,307 (2003).
- 25. Pavlishchuk V.V., Kolotilov S.V., Addison A.W., Prushan M.J., Butcher R.J. and Thompson L.K., Inorg. Chem., 38, 1759(1999).
- 26. Pouchert C.J., The Aldrich Library of Infrared Spectra (3rd Ed.), Aldrich Chemical Company, Milwaukee, Wisconsin, 1981.
- 27. Kopel R, Travniček Z., Zbohl R. and Marek J., Polyhedron, 23, 2193 (2004).
- 28. Lever A.B.R, Inorganic Electronic Spectroscopy. Elsevier, Amsterdam, 1984.
- 29. Kopel R, Doležal K., Machała L. and Langer V., Polyhedron, (2006), (in press).
- 30. Costes J-R., Dahan F. and Laurent J-R, Inorg. Chem., 25, 413 (1986).
- 31. Kothe G., Ohmes E., Brickmann J. and Zimmermann H., Angew. Chem. Int. Ed. Engl., 10,938 (1971).
- 32. Hudson A. and Luckurst G.R., Mol. Phys., 13, 409 (1967).
- 33. Kothe G., Naujok A. and Ohmes E., Mol. Phys., 32, 1215 (1976).
- 34. Kothe G., Neugebauer F.A. and Zimmermann H., Angew. Chem. Int. Ed. Engl., 11, 830 (1972).
- 35. Tsukerblat B.S., Kuyarskaya B.Ya, Belinski M.L, Ablov A.V., Novorvortsev V.M. and Kalinnikov V.T., Theoret. Chim. Acta (Berlin), 38, 131 (1975).
- 36. Inoue M. and Kubo M., J. Coord. Chem., 6, 157 (1977).
- 37. Butcher R.J., O'Connor C.J. and Sinn E., Inorg. Chem., 20, 537 (1981).
- 38. Costes J.R, Dahan F. and Laurent J.R, Inorg. Chem., 25, 413 (1986).
- 39. Nakao Y, Nakamura H., Mori W., Samurai T., Suzuki S. and Nakahara A., Bull. Chem. Soc. Jpn., 59, 2755 (1987).
- 40. Smart J.S., Effective Field Theories of Magnetism, W.B. Saunders Comp., Philadelphia and London, 1966.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ6-0011-0020