Multinuclear NMR and MS Characterization of Silver(I) Perfluorocarboxylates Complexes with 1,4-Bis(diphenylphosphino)butane

Szymańska, I.; Goliński, A.; Pazderski, L.; Szłyk, E

Artykuł - szczegóły

Tytuł artykułu

Multinuclear NMR and MS Characterization of Silver(I) Perfluorocarboxylates Complexes with 1,4-Bis(diphenylphosphino)butane

Autorzy

Szymańska I. , Goliński A. , Pazderski L. , Szłyk E

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

Ag(I) perfluorinated carboxylates complexes with 1,4-bis(diphenylphosphino)butane (dppb) of general formulae [Ag2(dppb)(RCOO)2]n, where R = C2F5, C3F7, C4F9, C6F13, C8F17 have been prepared and characterized by MS, 1H, 13C, 19F, 31P NMR and IR spectroscopy. In the solid state Ag(I) compounds are most likely tetranuclear species bridged by both diphosphines and carboxylates, because MS studies revealed multinuclear metallated species with bridging dppb and carboxylates. Variable temperature (VT) 31P NMR spectra demonstrate that studied complexes form binuclear species bonded by diphosphine with intermolecular diphosphine exchange, in chloroform solution. Thermal studies of Ag(I) compounds revealed three stages decomposition processes (exothermic) resulting in metallic silver formation in the range 713-853 K.

Słowa kluczowe

silver(I) complexes diphosphines perfluorinated carboxylates MS NMR

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2007

Tom

Vol. 81, nr 3

Strony

299--311

Opis fizyczny

Bibliogr. 43 poz., rys.

Twórcy

autor

Szymańska I.

autor

Goliński A.

autor

Pazderski L.

autor

Szłyk E

Faculty of Chemistry, Nicolaus Copernicus University, 87-100 Toruń, Gagarina 7, Poland

Bibliografia

1. Ohkouchi M., Masui D., Yamaguchi M. and Yamagishi T., J. Mol. Catal. A: Chem., 170, l (2001).
2. Kitagawa S., Kondo M., Kawata S., Wada S., Maekawa M. and Munakata M., Inorg. Chem., 34, 1455 (1995).
3. Puddephatt R.J., J. Chem. Soc. Rev., 12, 99 (1983).
4. Garrou P.E., Chem. Rev., 81, 229 (1981).
5. Yang R., Hou Y., Xue B., Wang D. and Jin D., Trans. Met. Chem., 21, 28 (1996).
6. Schmidbaur H., Bissinger R, Lachmann J. and Steigelmann O., Z. Naturforsch., B47, 1711 (1992).
7. Brandys M.C., Jennings M.C. and Puddephatt R.J., J. Chem. Soc. Dalton Trans., 24, 4601 (2000).
8. Brandys M.C. and Puddephatt R.J., Chem. Commun., 1280 (2001).
9. van Calcar P.M., Olmstead M.M. and Balch A.L., Inorg. Chem., 36, 5231 (1997).
10. Brandys M.C. and Puddephatt R.J., J. Am. Chem. Soc., 123,4839 (2001).
11. Black J.R., Levason W., Spicer M.D. and Webster M., J. Chem. Soc. Dalton Trans., 20, 3129 (1993).
12. Comba R, Katsichtis C., Nuber B. and Pritzkow H., Eur. J. Inorg. Chem., 777 (1999).
13. Xie W., Wang R., Xiong Y., Yang R., WangD., Jin D., Chen L. And Luo B., Chinese J. Struct. Chem., 16,293 (1997).
14. Yang R., Yang Y, Lin K., Wang D., Jin D., Chen J. and Li M., J. Chemistry, 55, 1198 (1997).
15. Affandi D., Berners-Price S.J., Effendy, Harvey P.J., Healy P.C., Ruch B.E. and White A.H., J. Chem. Soc. Dalton Trans., 8, 1411 (1997).
16. Berners-Price S.J., Johnson R.K., Mirabelli C.K., Faucette L.F., McCabe F.L. and Sadler P.J., Inorg. Chem., 26, 3383 (1987).
17. Berners-Price S.J., Brevard C., Pagelot A. and Sadler P.J., Inorg. Chem., 24, 4278 (1985).
18. Berners-Price S.J. and Sadler P.J., Inorg. Chem., 25, 3822 (1986).
19. Szłyk E., Kucharek R. and Szymańska L, Polish J. Chem., 75, 337 (2001).
20. Szłyk E., Szymańska L, Surdykowski A., Głowiak T., Wojtczak A. and Goliński A., J. Chem. Soc. Dalton Trans., 17, 3404 (2003).
21. Szłyk E., Kucharek R. and Szymańska L, J. Coord. Chem., 53, 55 (2001).
22. Grodzicki A., Łakomska L, Piszczek R, Szymańska I. and Szłyk E., Coord. Chem. Rev., 21-22, 2232 (2005).
23. Szłyk E., Kucharek R., Szymańska I. and Pazderski L., Polyhedron, 22, 3389 (2003).
24. Szłyk E., Kucharek R., Szymańska I. and Pazderski L., Polish J. Chem., 19, 1705 (2005).
25. Szłyk E., Łakomska L and Grodzicki A., Thermochim. Acta, 223, 207 (1993).
26. Edwards D.A., Harker R.M., Mahoń M.F. and Molloy K.C., Inorg. Chim Acta, 328, 134 (2002).
27. Łakomska L, Grodzicki A. and Szłyk E., Thermochim. Acta, 303, 41 (1997).
28. Lu Y.-F., Takai M., Shiokawa T. and Aoyagi Y, J. Appl. Phys., 33, 1313 (1994).
29. Lu Y.-F., Takai M., Nagamoto S., Kato K. and Namba S., Appl. Phys. A - Mater. Sci. Process, 54, 51 (1992).
30. Samoilenkov S., Stefan M., Wahl G., Paramanov S., Kuzmina N. andKaul A., Chem. Vap. Deposition, 8, 74 (2002).
31. Paramanov S., Samoilenkov S., Papucha S., MalkerovaL, Alikhanyan A., Kuzmina N., Troyanov S. and Kaul A., J. Phys. IV, 11, 645 (2001).
32. Hasse T., Kohse-Höinghaus K., Atkan B., Schmidt H. and Lang H., Chem. Vap. Deposition, 9, 145 (2003).
33. Schmidt H., Shen Y., Leschke M., Hasse Th., Kohse-Höinghaus K. and Lang H., J. Organometallic Chem., 669, 25 (2003).
34. Adams S.K., Edwards D.A. and Richards R., Inorg. Chim. Acta, 12, 163 (1975).
35. Pierce J.L., Busch K.L., Cooks R.G. and Walton R.A., Inorg. Chem., 22, 2492 (1983).
36. Roberts G.D. and White E., Organic Mass Spectrometry, 16, 546 (1981).
37. BonningtonL.S.,Coli R.K.,Gray E. J.,Flett J.I.and Henderson W., Inorg. Chem.,290,213 (1999).
38. Szłyk E. and Szymańska L, Polyhedron, 18, 2941 (1999).
39. Nakamoto K., Infrared Spectra of Inorganic and Coordination Compounds, 3rd edition, Wiley, New York (1978) p. 232, p. 333.
40. Edwards H.G.M., Lewis I.R. and Turner P.H., Inorg. Chim. Acta, 216, 191 (1994).
41. Edwards D.A. and Richards R., J. Chem. Soc. Dalton Trans., l, 637 (1975).
42. Integrated Spectral Data Base System for Organic Compounds, National Institute of Advanced Industrial Science and Technology, Tsukuba, Ibaraki, Japan; http://www.aist.go.jp/RIODB/SDBS/(2004).
43. Powder Diffraction File, Sets 4-783, International Centre for Difrraction Data (JCPDS), USA (1977).

Typ dokumentu

Bibliografia

Identyfikator YADDA

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