Excess Volumes and Adiabatic Cmpressibilities of Binary Mixtures of Cyclohexanol + Glycerol at 298.15h

• Autorzy: Zorębski E.
• Języki publikacji: EN

Abstrakty

EN

The excess values of the molar volume and molar adiabatic compressibility as well as adiabatic compressibility coefficient were estimated for binariey mixtures of cyclohexanol + glycerol at 298.15K. Also deviations of the ultrasonic speed from the chosen additivity rules were determined. Both the excess quantities as well as the speed of ultrasound deviations are expressed by the Redlich-Kister polynomials and aisscused in term of molecular interactions.

Słowa kluczowe

EN

compressibility; speed of ultrasound; excess; binary mixtures; alcohols

• Wydawca: Silesian Division of Polish Acoustical Society
• Czasopismo: Molecular and Quantum Acoustics
• Rocznik: 2002
• Tom: Vol. 23
• Strony: 463--472
• Opis fizyczny: Bibliogr. 17 poz., rys.

Twórcy

autor

Zorębski E.

• alcohols,

Bibliografia

• 1. M.Waciński, K.Bebek, E.Zorębski, Compressibility of binary mixtures of associating liquids, Arch. Acoustics, 9(3), 355-362 (1984).
• 2. M.Waciński, E.Zorębski, K.Bebek, Dynamic and static viscosity and elasticity moduli of binary mixtures of polyhydroxy alcohols, Arch. Acoustics, 9(3), 363-380 (1984).
• 3. S.Ernst, K.Bebek, E.Zorębski, E.Soczkiewicz, Rheological and volume effects in liquid binary mixtures of polyhydroxyalcohols, Acta Phys. Slov., 36(1), 31-42 (1986).
• 4. E.Zorębski, S.Ernst, Viscoelastic properties of binary liquid hydroxyl mixtures in the light of local molecular order, Acta Phys.Slov., 40(1), 48-57 (1990).
• 5. S.Ernst, E.Zorębski, K.Bebek, Viscolelastic Behaviour of Binary Polyhydroxy Liquid Systems: Glycerol-Butanediol-1,3 and Glycerol-2-Methylpentanediol-2,4, Acustica, 72. 81-89,(1990).
• 6. E.Zorębski, A.Zak, Acoustic and Volumetric Investigations of 1,5-pentanediol+Glycerol at 298.15 K; Comparison with Recalculated Data for: 1,3-Butanediol+Glycerol and 2-Methyl-2,4-Pentanediol+Glycerol, Z.Phys.Chemie, 210, 223-233 (1999).
• 7. E.Zorębski, J.Nurek, Ultrasonic Speeds, Molar Excess Volumes and Adiabatic Compressi-bilities of the 1 -Butanol + Glycerol System at 298.15 K, Z.Phys.Chemie, 216. 895-904 (2002).
• 8. G.Douheret, A.Khadir, A.Pal, Thermodynamic characterization of the water+methanol system, at 298.15 K, Thermochim. Acta, 142, 219-243 (1989).
• 9. G.Douheret, M.I.Davis, J.C.R.Reis, M.J.Blandamer, Isentropic Compressibilities -Experi-mental Origin and the Quest for their Rigorous Estimation in Thermodynamically Ideal Liquid Mixtures, Chem. Phys. Chem., 2, 148-161 (2001).
• 10. C.Wójtowicz, Ultradźwiękowe badania mieszanin cieczy silnie zasocjowanych: gliceryna- cykloheksanol, gliceryna-pentanodiol-1,5, M.Sc. Thesis, Uniwersytet Śląski, Katowice 1988.
• 11. E.Zorębski, S.Ernst, Zestaw do pomiaru prędkości fazowej fali ultradźwiękowej w cieczach metodą otwartej pętli elektroakustycznej, Akustyka Mol. i Kwant., 9, 101-106 (1988).
• 12. J.A.Riddick, W.B.Bunger, T.K.Sakano, Organic Solvents, 4th ed., Wiley, NY 1986.
• 13. B.Vargaftik, Sprawocznikpo tieplofiziczieskim svoistwam gazów i żidkostiej, Izd. Nauka, Moskwa 1972.
• 14. D.Hopfe, Data Compilation of FIZ Chemie, Germany 1990.
• 15. O.Kiyohara, J-P.E.Grolier, G.C.Benson, Excess Volumes, Ultrasonic Velocities and Adiabatic Compressibilities for Binary Cycloalkanol Mixtures at 25°C, Can. J. Chem., 52, 2287-2293 (1974).
• 16. M.Gepert, S.Ernst, Acoustic Properties of Pure Alcohols and Binary Mixtures Containing Alcohols, Mol. Quant. Acoust., 22, 77-84 (2001).