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Effect of Humidity on Nh3 Gas Sensitivity of Nafion R /WO3 Sensing Structure of Spr Sensor

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The paper presents an optical sensor that permits to detect and to measure the concentration of ammonia gas in a gaseous medium and the effect of humidity on the NH3 detection capability of sensing structure of optical sensor was also investigated. The presence of water vapour, functioning as the interference gas, led to the lowering of the NH3 response of the sensor in a humid atmosphere. An optical sensor of ammonia gas, based on the surface plasmon resonance (SPR) method has been investigated. The surface plasmon resonance (SPR) is very sensitive, and so is the optical technique used in chemical sensing. NafionŽ/WO3 stack films on plasmon active Au film was used as the sensing structure of SPR sensor. The gold layer was coated by means of vacuum evaporation on a BK7 substrate. The thickness of Au was about 50 nm. The sensing structures were coupled on immersion oil with a prism coupler. Although NafionŽ film had hydrophilic character absorbs 22% by weight of water, the influence of humidity on the SPR sensor response was not as large as expected due to construction of the sensing structure. A change of the intensity of light of the plasmon dip was observed when chemical active stack films (Nafion R/WO3) was exposed to varying concentrations of NH3 in a dry and humid atmosphere. Optical ammonia gas SPR sensor display a very fast response time and a fast regeneration time at room temperature not only in a dry atmosphere, but also in a humid atmosphere.
Rocznik
Tom
Strony
205--215
Opis fizyczny
Bibliogr. 25 poz., rys.
Twórcy
autor
  • Dept. of Optoelectronics, Institute of Physics, Silesian University of Technology, 2 Krzywoustego Str., 44-100 Gliwice, Poland, tel. +48 32 2372539, fax +48 32 237 2216
autor
  • Dept. of Optoelectronics, Institute of Physics, Silesian University of Technology, 2 Krzywoustego Str., 44-100 Gliwice, Poland
autor
  • Dept. of Optoelectronics, Institute of Physics, Silesian University of Technology, 2 Krzywoustego Str., 44-100 Gliwice, Poland
Bibliografia
  • 1. M. Vidotti, et al., “Reduction of interference signal of ascorbate and urate in poly(pyrrole)-based ammonia sensors in aqueous solutions”, Electrochimica Acta 49, 2004, 3665–3670
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  • 5. M. Aslam, V.A. Chaudhary, I.S. Mulla, S.R. Sainkar, A.B. Mandale, A.A. Belhekar, K. Vijayamohanan, „A highly selective ammonia gas sensor using surface-ruthenated zinc oxide”, Sensors and Actuators B75, 1999, 162–167
  • 6. S.S. Sunu, E. Prabhu, V. Jayaraman, K.I. Gnanasekar, T.K. Seshagiri, T. Gnanasekaran, “Electrical conductivity and gas sensing properties of MoO3, Sensors and Actuators B 101, 2004, 161–174
  • 7. M. Blo, M.C. Carotta, S. Galliera, S. Gherardi, A. Giberti, V. Guidi, C. Malagù, G. Martinelli, M. Sacerdoti, B. Vendemiati, A. Zanni, “Synthesis of pure and loaded powders of WO3 for NO2 detection through thick film technology” Sensors and Actuators B103, 2004, 213–218
  • 8. B. T. Marquis, J. F. Vatelino, “A semiconducting metal oxide sensor array for the detection of NOx nad NH3”, Sensors and Actuators B77, 2001, 100–110
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  • 10. H. Hu, M. Trejo, et al., “Adsorption kinetics of optochemical NH3 gas sensing with semiconductor polyaniline films”, Sensors and Actuators B82, 2002, 14–23
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  • 18. E. Maciak, Z.Opilski, A.Opilski, “Surface Plasmon Resonance Liquid Sensor based on prism coupler in the Kretschmann geometry”, Molecular and Quantum Acoustic 21, 2000, 173–178
  • 19. J.Ignac-Nowicka, T.Pustelny, Z.Opilski, E. Maciak, W. Jakubik, M. Urbańczyk, „Examination of thin films of phthalocyanines in plasmon system for their application in NO2 sensors”, Optical Engineering, vol.42, No 10 2003, 2978–2986
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  • 23. V. Misra, H. Mishra, H.C. Joshi, T.C. Pant, „An optical pH sensor based on excitation energy transfer in Nafion film”, Sensors and Actuators B 82, 2002, 133-141
  • 24. E. Maciak, Z. Opilski, T. Pustelny, A. Stolarczyk, Optical sensing of ammonia gas in air using the SPR technique, Proceedings of SPIE Integrated Optics: Theory and Application. vol. 5956 (SPIE, Bellingham, WA, 2005) 59521K1- K9
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ6-0007-0089
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