Speed Of Ultrasound And Thermodynamic Properties Of 1-Butanol In Binary Liquid Mixtures At 293.15 K

• Autorzy: Bebek K.
• Języki publikacji: EN

Abstrakty

EN

The speeds of ultrasound in and densities of binary solutions of 1-butanol in hexane and cyclohexane were measured on the whole concentration range at 293.15 K. The experimental results in connection with literature data were used to calculate the isothermal compressibility coefficients and isochoric molar heat capacities for the pure components, as well as the excess molar volumes, excess adiabatic compressibilities, free volumes and the free intermolecular lengths for the binaries under test. The dependences of the excess properties on the mixture composition were compared and discussed in terms of the free intermolecular length and other factors affecting the solvation and self-association effects.

Słowa kluczowe

EN

binary liquid mixtures; speed of ultrasound; density; free volume; excess molar volume; free intermolecular length

• Wydawca: Silesian Division of Polish Acoustical Society
• Czasopismo: Molecular and Quantum Acoustics
• Rocznik: 2005
• Tom: Vol. 26
• Strony: 7--13
• Opis fizyczny: Bibliogr. 20 poz., rys.

Twórcy

autor

Bebek K.

• University of Silesia, Institute of Chemistry, Szkolna 9, 40-006 Katowice, Poland,

Bibliografia

• 1. H.T.French, J.Sol.Chem., 12(12), 869 (1983)
• 2. K.Bebek, S.Ernst, Arch.Acoust., 15(3-4), 239 (1990)
• 3. K.Bebek, E.Grzywna, S.Ernst, Arch.Acoust., 22(1), 93 (1997).
• 4. K.Bebek, Mol.Quant.Acoust., 24, 17 (2003)
• 5. R.H.Stokes, J.Chem.Soc.Faraday Trans. I, 73, 1140 (1977)
• 6. S.Ernst, et al., Acoust.Lett., 15, 123 (1992)
• 7. E.Zorębski, et al., Proc. World Congress of Ultrasonics, Berlin 1995, p.547-550.
• 8. S.Ernst, W.Marczak, W.Kmiotek, J.Chem.Eng.Data, 41(1),128 (1996)
• 9. J.Troncoso, et al., J.Chem.Eng.Data, 45, 594 (2000)
• 10. M.F.Bolotnikov, et al., J.Chem. Eng.Data, 50, 1095 (2005)
• 11. J.A.Riddick, W.A.Bunger, Organic Solvents, 3rd Edn., Wiley NY 1977
• 12. E.S.Domalski, E.D.Hearing, J.Phys.Chem.Ref.Data, 19,(4) 881 (1990)
• 13. A.Weissberger, Technique of organic chemistry,VII Interscience Publishers, London 1955
• 14. G.C.Benson, O.Kiyohara, J.Chem.Thermodyn., 11, 1061 (1979)
• 15. B.Jacobson, Acta Chem.Scand., 6, 1485 (1952).
• 16. B.Jacobson, Acta Chem.Scand., 9, 997 (1955)
• 17. C.V.Chaturvedi, S.Prakash, Acustica, 27, 249 (1972)
• 18. J.C.Kincaid, H.Eyring, J.Chem.Phys., 6, 620 (1938)
• 19. T.Hofman, Fluid Phase Equilibria, 55, 271 (1990)
• 20. S.J.Tangeda, S.Nallani, J.Chem.Eng.Data, 50, 89 (2005)