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Relaxation Phenomena In The Nematic Phase of Liquid Crystal Near Phase Transition

Autorzy
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Absorption of ultrasonic longitudinal waves in the nematic liquid crystal 1-(trans- 4-hexylcyclohexyl)-4-isothiocyanatobenzene (6CHBT) was measured in the temperature (24-56oC) and frequency (3.2-100 MHz) ranges. In the region of the phase transition the anomalous absorption has been observed. This absorption rapidly increases when the frequency of the ultrasonic wave decreases. The experimental results for the nematic phase were analysed and two relaxation processes have been found. Relaxation parameters for both processes were calculated. The process with the longer relaxation time is connected with the order parameter changes. The isomeric changes in the hexyl chain of the 6CHBT molecule is the origin of the process characterized by the shorter relaxation time.
Rocznik
Tom
Strony
7--13
Opis fizyczny
Bibliogr. 9 poz., rys.
Twórcy
autor
  • Institute of Fundamental Technological Research, Polish Academy of Sciences, Świętokrzyska 21, 00-049 Warszawa, Poland, abalcerz@ippt.gov.pl
Bibliografia
  • 1. P.G. de Gennes, J. Prost, Physics of Liquid Crystals, Claredon Press, Oxford 1998.
  • 2. Y.V. Sperkach, V.S. Sperkach, O. Aliokhin, A.L. Strybulevych, M. Masuko, Temperature dependence of acoustical relaxation times involving the vicinity of N-I phase transition point in 5CB liquid crystal, Mol.Cryst. and Liq.Cryst. 366, 183-202 (2001).
  • 3. H. Imura, K. Okano, Theory of anomalous ultrasonic absorption and dispersion of nematic liqiud crystals just above the clearing point, Chem.Phys.Lett. 19, 387-390 (1973).
  • 4. S. Nagai, P. Martinoty, S. Candau, Ultrasonic investigation of nematic liquid crystals in the isotropic and nematic phases, J.Phys. (Paris) 37, 769-780 (1976).
  • 5. G.G. Natale, The contribution of ultrasonic measurements to the study of liquid crystals. I. Nematics, J.Acoust.Soc.Am. 63, 1250-1278 (1978).
  • 6. L.D. Landau, I.M. Khalatnikov, Anomalous sound attenuation near points of the second order phase transition, Dokl.Akad.Nauk. SSSR 96, 469-472 (1954).
  • 7. K. Muralidhar, M.L.S. Swamy, S. Nana Rao, K. Subba Rao, Ultrasonic study of the smectic-A – isotropic phase transition in p-(n-octoxy)benzylidene-p-(n-butyl)aniline, Phys.Rev.A 33, 3477-3480 (1986).
  • 8. A. Balcerzak, R. Płowiec, P. Kiełczyński, A. Juszkiewicz, Ultrasonic investigations of aqueous solutions of α-cyclodextrin and amphiphilic substances having different “heads” and identic “tails”, Archives of Acoustics 37, 361-371 (2002).
  • 9. C.A. Castro, A. Hikata, C. Elbaum, Ultrasonic attenuation anisotropy in a nematic liquid crystal, Phys.Rev.A 17, 353-362 (1978).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ6-0007-0072
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