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Template condensation of the metal ions with hydrazine, 2,4-pentanedione and acetaldehyde in a 1:4:2:2 molar ratio resulted in the formation of a new series of 16-membered octaazamacrocyclic complexes: dichloro/nitrato [2,5,8,10,13,16-hexamethyl-3,4,6,7,11, 12,14,15-octaazacyclohexadecane-2,7,10,15-tetraene)metal(II)], [MLX2] (M = Fe(II), Co(II), Ni(II), Cu(II) and Zn(II); X = Cl or NO3). The overall geometry and stereochemistry of the complexes have been characterized by elemental analyses, IR, 1HNMR, EPR, UVvisible, magnetic susceptibility and conductivity measurements. An octahedral geometry is suggested for all of the complexes. The conductivity data suggest that the complexes are non-ionic in nature.
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Strony
1449--1455
Opis fizyczny
Bibliogr. 35 poz.
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autor
autor
autor
- Division of Inorganic Chemistry, Department of Chemistry, Aligarh Muslim University, Aligarh - 202002, India
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ6-0007-0037