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Template Synthesis of 16-Membered Octaazamacrocyclic Complexes of Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) Ions

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Template condensation of the metal ions with hydrazine, 2,4-pentanedione and acetaldehyde in a 1:4:2:2 molar ratio resulted in the formation of a new series of 16-membered octaazamacrocyclic complexes: dichloro/nitrato [2,5,8,10,13,16-hexamethyl-3,4,6,7,11, 12,14,15-octaazacyclohexadecane-2,7,10,15-tetraene)metal(II)], [MLX2] (M = Fe(II), Co(II), Ni(II), Cu(II) and Zn(II); X = Cl or NO3). The overall geometry and stereochemistry of the complexes have been characterized by elemental analyses, IR, 1HNMR, EPR, UVvisible, magnetic susceptibility and conductivity measurements. An octahedral geometry is suggested for all of the complexes. The conductivity data suggest that the complexes are non-ionic in nature.
Rocznik
Strony
1449--1455
Opis fizyczny
Bibliogr. 35 poz.
Twórcy
autor
autor
autor
  • Division of Inorganic Chemistry, Department of Chemistry, Aligarh Muslim University, Aligarh - 202002, India
Bibliografia
  • 1.Bernhardt P.V and Sharpe P.C., Inorg. Chem., 39, 4123 (2000).
  • 2.Konig B., Gallmeier H.C. and Klinke R.R., Chem. Commun., 2390 (2001).
  • 3.Sibert J.W., Cory A.H. and Córy J.G., Chem. Commun., 154 (2002).
  • 4.Campbell V.D., Parson EJ. and Pennington W.T., Inorg. Chem., 32, 1773 (1993).
  • 5.Zinic M. and Skaric Y, J. Org. Chem., 53, 2582 (1988).
  • 6.Behret H., Clauberg W. and Sandstede G., J. Electroanal. Chem., 14, 393 (1976).
  • 7.Hovland R., Gloyard C., Aasen AJ. and Klaveness J., J. Chem. Soc. Perkin Trans., 2, 929 (2001).
  • 8.Pope S.J.A., Kenwright A.M., Boote Y.A. and FaulknerS., J. Chem. Soc., Dalton Trans., 3780(2003).
  • 9.Beeby A., Bushby L.M., Maffeo D. and Willams J.A.G., J.Chem. Soc., Dalton Trans., 4854 (2002).
  • 10.Anniebligh S.W., Choi N., Evagorou E.G., Mcpartlin M. and White K.N., J. Chem. Soc., Dalton Trans.,3169(2001).
  • 11.Adams H., Bastida R., Fenton D.E., Macias A., Spey S.E. and Valencia L., J. Chem. Soc., Dalton Trans., 4131(1999).
  • 12.Trommel J.S. and Marzilli L.G., Inorg. Chem., 40, 4374 (2001).
  • 13.Lu X., Geng Z., Wang Y., Lu B. and Kang J., Synth. React. Inorg. Met.-Org. Chem., 32, 843 (2002).
  • 14.Radecka-Paryzek W, Inorg. Chim. Acta, 35, 349 (1979).
  • 15.Peng S.M. and Goedken Y.L., J. Chem. Soc., Chem. Commun., 3, 62 (1973).
  • 16.Fenton R.R., Lindoy L.F., Price J.R., Skelton W. and White A.B., Aust. J. Chem., 56,1141 (2003).
  • 17.Formica M., Fusi Y, Giorgi L., Palma P. and Pontellini R., Eur. J. Org. Chem., 402 (2002).
  • 18.Reilley C.N., Schmid R.W. and Sadak F.S., J. Chem. Edu., 36, 619 (1959).
  • 19.Vogel A.L, "A Text Book of Quantitative Inorganic Analyses", 3rd Edn., Longmans, London, 1961, p. 433.
  • 20.Geary W.J., Use of Conductivity Measurements in Organic Solvents for the Characterization of Coordination Compounds., Coord. Chem. Rev., 7, 81 (1971).
  • 21.Shakir M., Yarkey S.P., Firdaus F. and Hameed P.S., Polyhedron, 13, 2319 (1994).
  • 22.Cruz C., Carvaho S., Delgado R., Felix Y. and Goodfellow B. J., Dalton Trans., 3172 (2003).
  • 23.Rana Y.B., Singh P., Singh D.P. and Teotia M.P., Polyhedron, l, 377 (1982).
  • 24.Shakir M., Yarkey S.P. and Hameed P.S., Polyhedron, 13, 1355 (1994).
  • 25.Jain M.C., Srivastava A.K. and Jain P.C., Inorg. Chim. Acta, 23, 199 (1977).
  • 26.Hay R.W., Ali M.A. and Jeragh B., J. Chem. Soc., Dalton Trans., 2763 (1988).
  • 27.Cabeza J.A., Riviera V., Pellingbelli M.A. and Tripicchio A., J. Org. Met. Chem., 23, 376 (1989).
  • 28.Silverstein R.M., Spectrometric Identification of Organic Compounds, 4th edn., John Wiley, New York, 1981.
  • 29.Burgess K., Lim D. and Kanho K., J. Org. Chem., 59, 2179 (1994).
  • 30.Ahuja I.S. and Tripathi S., Indian J. Chem., 30(A), 1060 (1991).
  • 31.Proctor I.M., Hathaway B.J. and Nicholls P., J. Chem. Soc., A, 1678 (1968).
  • 32.Mazumdar A.K.D., Dal S.C., Karmakar P.K., Saha N.K. and Banerg K.D., J. Ind. Chem. Soc., 69, 761 (1992).
  • 33.Kivelson D. and Neiman R.R., J .Chem. Phys., 35, 149 (1961).
  • 34.Lever A.B.P., Inorganic Electronic Spectroscopy, 2nd Edn., Elsevier, Amsterdam, 1984, p. 318.
  • 35.Cotton F.A. and Wilkinson G., Advanced Inorganic Chemistry, 5th Edn. Wiley, New York, 1988.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ6-0007-0037
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