Hydroxylation of Alkanes Using H2O2 or tert-BuOOH Catalyzed by Silica-based Fe(III) Interphase Catalysts

• Autorzy: Luo Y. , Zhang L. , Zong M. , Ménage S. , Fontecave M.
• Języki publikacji: EN

Abstrakty

EN

Two novel silica-based organic-inorganic hybrid (interphase) Fe(III) catalysts have been successfully prepared by the flexible ligandmethod, characterized and applied to the efficient catalytic oxidation of various types of substrates using 30% H2O2 or tert-BuOOH under mild conditions. The catalysts can be recovered and reused for four reaction cycles with total turnover numbers being about 29 using cyclohexene as the substrate. The mechanism for the O-O bond cleavage was proposed based on the results in combination with previous experimental results.

Słowa kluczowe

EN

methane monooxygenase; biomimetic hydroxylation; hydrogen peroxide; interphase catalyst

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2006
• Tom: Vol. 80, nr 8
• Strony: 1407--1414
• Opis fizyczny: Bibliogr. 31 poz., rys.

Twórcy

autor

Luo Y.

autor

Zhang L.

autor

Zong M.

autor

Ménage S.

autor

Fontecave M.

• School of Biological Sciences and Biotechnology, and Department of Chemical Engineering, School of Chemical and Energy Engineering, South China University of Technology, Guangzhou 510640, P. R. China

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