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Interpretation of isotope effects on the solubility of gases

Autorzy
Treść / Zawartość
Identyfikatory
Warianty tytułu
Konferencja
Proceedings of the International Conference “2001 an Isotope Odyssey: New Application for a New Millenium", June 24-29, 2001, Zakopane, Poland
Języki publikacji
EN
Abstrakty
EN
Experimental results concerning the isotope effect on the solubility of gases are reviewed and the theory of the isotope effect on Henry's law constants is derived in terms of the statistical mechanical theory of condensed phase isotope effects. The performance of the method is demonstrated by detailed analysis of some of the available experimental data on solubility isotope effect.
Czasopismo
Rocznik
Strony
53--57
Opis fizyczny
Bibliogr. 24 poz., rys.
Twórcy
autor
  • KFKI Atomic Energy Research Institute, 1525 Budapest 114 P.O. Box 49, Hungary, Tel.: 36 1/ 3922222, Fax: 36 1/ 3922299, jancso@sunserv.kfki.hu
Bibliografia
  • 1. Benson BB, Krause Jr D, Peterson MA (1979) The solubility and isotopic fractionation of gases in dilute aqueous solution. I. Oxygen. J Solution Chem 8:655–690
  • 2. Benson BB, Krause Jr D (1980) Isotopic fractionation of helium during solution: a probe for the liquid state. J Solution Chem 9:895–909
  • 3. Benson BB, Krause Jr D, Romer RH, Frank HS, Wen W-Y (1981) Response to the comments by P. Bopp and M. Wolfsberg. J Solution Chem 10:363–364
  • 4. Bigeleisen J (1961) Statistical mechanics of isotope effects on the hermodynamic properties of condensed systems. J Chem Phys 34:1485–1493
  • 5. Blaga L, Blaga LM, Ciobotaru T (1974) Determination of the isotopic fractionation factor of hydrogen during the dissolving of natural methane in water strata. Isotopenpraxis 10:201–204
  • 6. Bopp P, Wolfsberg M (1981) Comments on a model for isotope effects on Henry’s law constants in aqueous solution. J Solution Chem 10:357–361
  • 7. Cook MW, Hanson DN, Alder BJ (1957) Solubility of hydrogen and deuterium in nonpolar solvents. J Chem Phys 26:748–751
  • 8. Costa Gomes MF, Lopes JNC, Mink J, Bacsik Z, Jancsó G (2000) Interpretation of the isotope effect on the solubility of methane in water by using spectroscopic data (abstract). XXV European Congress on Molecular Spectroscopy, Coimbra, p 233
  • 9. Costa Gomes MF, Grolier J-P (2001) Determination of Henry’s law constants for aqueous solutions of tetradeuteriomethane between 285 and 325 K and calculation of the H/D isotope effect. Phys Chem Chem Phys 3:1047–1052
  • 10. Dang LX, Bopp P, Wolfsberg M (1989) Evaluation of isotope effects on Henry’s law constants by a molecular dynamics technique. Z Naturforsch 44a:485–491
  • 11. El-Nour FA, Harting P, Schütze H (1977) Thermodynamic carbon isotope effect for solubility of ethane in water. Isotopenpraxis 13:296–298
  • 12. Geßler R, v. Gehlen K (1986) Investigation of sulfur isotope fractionation between H2S gas and aqueous solutions. Fresen J Anal Chem 324:130–136
  • 13. Harting P, Schütze H, Christoph G (1976) Der thermodynamische Kohlenstoffisotopieeffekt im System CH4-H2O. Isotopenpraxis 12:232–234
  • 14. Harting P (1978) Der thermodynamische KohlenstoffIsotopieeffekt im System CH4-H2O. II. Isotopenpraxis 14:99–101
  • 15. Harting P (1981) Der thermodynamische Kohlenstoffisotopieeffekt im System CH4-H2O. III. Isotopenpraxis 17:164–167
  • 16. Hillier IH, Walkley J (1963) Quantum effects in dilute solutions. Nature 198:257–258
  • 17. Jancsó G, Van Hook AW (1974) Condensed phase isotope effects (especially vapor pressure isotope effects). Chem Rev 74:689–750
  • 18. Klots CE, Benson BB (1963) Isotope effect in the solution of oxygen and nitrogen in distilled water. J Chem Phys 38:890–892
  • 19. Krause Jr D, Benson BB (1989) The solubility and isotopic fractionation of gases in dilute aqueous solution. IIa. Solubilities of the noble gases. J Solution Chem 18:823–873
  • 20. Muccitelli J, Wen W-Y (1978) Solubilities of hydrogen and deuterium gases in water and their isotope fractionation factor. J Solution Chem 7:257–267
  • 21. Szaran J (1996) Experimental investigation of sulphur isotopic fractionation between dissolved and gaseous H2S. Chem Geol (Isotope Geoscience Section) 127:223–228
  • 22. Taubmann G, Witschel W (2000) Calculation of the isotopic fractionation of helium in aqueous solution from effective potentials. J Solution Chem 29:799–814
  • 23. Vogel JC, Grootes PM, Mook WG (1970) Isotopic fractionation between gaseous and dissolved carbon dioxide. Z Physik 230:225–238
  • 24. Volk H, Halsey Jr GD (1960) Solubility of hydrogen and deuterium in liquid argon. J Chem Phys 33:1132–1139
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ6-0006-0067
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