Formation of Br2 '-, BrSCN'- and (SCN)2'-intermediates in the ionic liquid methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide. Pulse radiolysis study

Grodkowski, J.; Nyga, M.; Mirkowski, J.

Artykuł - szczegóły

Tytuł artykułu

Formation of Br2 '-, BrSCN'- and (SCN)2'-intermediates in the ionic liquid methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide. Pulse radiolysis study

Autorzy

Grodkowski J. , Nyga M. , Mirkowski J.

Treść / Zawartość

Pełne teksty:

Formation of Br2·-, BrSCN·- and (SCN)2·- intermediates.pdf

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Warianty tytułu

Konferencja

Proceedings of the XIII Scientific Meeting of the Polish Radiation Research Society, Memorial to Maria Skłodowska-Curie, 13-16 September 2004, Łódź, Poland

Języki publikacji

Abstrakty

The reactions of Br2 '- anion radicals with thiocyanate anions in the ionic liquid methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide (R4NNTf2) were studied by pulse radiolysis. Reaction of solvated electrons with BrCH2CH2Br (DBE), k = (1 2)×108 L.mol 1.s 1, leads to the production of Br2'- anion radicals. The intermediate absorption spectra following pulse radiolysis of DBE/SCN-/Br-/ solutions in R4NNTf2 correspond to Br2 '-, BrSCNo- and (SCN)2'- anion radicals. The participation of these radicals in the spectra changes with progressing reactions and depends on the concentration Br- and SCN- in the solution.

Słowa kluczowe

ionic liquids pulse radiolysis Br2

Wydawca

Institute of Nuclear Chemistry and Technology

Czasopismo

Nukleonika

Rocznik

2005

Tom

Vol. 50,suppl.2

Strony

35--38

Opis fizyczny

Bibliogr. 20 poz., rys.

Twórcy

autor

Grodkowski J.

jangrod@orange.ichtj.waw.pl

Department of Radiation Chemistry and Technology, Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: +48 22-8112347, Fax: +48 22-8111532

autor

Nyga M.

Department of Radiation Chemistry and Technology, Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: +48 22-8112347, Fax: +48 22-8111532

autor

Mirkowski J.

Department of Radiation Chemistry and Technology, Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: +48 22-8112347, Fax: +48 22-8111532

Bibliografia

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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUJ6-0005-0021